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Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water

Organophosphate-based pesticides, such as diazinon, are among the most toxic organic contaminants to human and environment. Effective removal of diazinon from contaminated water sources is critical. Zirconium Metal−organic frameworks (Zr-MOFs) are promising candidates for the removal of organic cont...

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Autores principales: Diab, Kamal E., Salama, Eslam, Hassan, Hassan Shokry, El-moneim, Ahmed Abd, Elkady, Marwa F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8623664/
https://www.ncbi.nlm.nih.gov/pubmed/34833167
http://dx.doi.org/10.3390/polym13223869
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author Diab, Kamal E.
Salama, Eslam
Hassan, Hassan Shokry
El-moneim, Ahmed Abd
Elkady, Marwa F.
author_facet Diab, Kamal E.
Salama, Eslam
Hassan, Hassan Shokry
El-moneim, Ahmed Abd
Elkady, Marwa F.
author_sort Diab, Kamal E.
collection PubMed
description Organophosphate-based pesticides, such as diazinon, are among the most toxic organic contaminants to human and environment. Effective removal of diazinon from contaminated water sources is critical. Zirconium Metal−organic frameworks (Zr-MOFs) are promising candidates for the removal of organic contaminants from wastewater. Herein, we report the adequacy of a bio based Zr-MOF named MIP-202 for the removal of diazinon from water. On the other hand, the use of these materials in powder form is not workable, the development of scalable and economical processes and integrative of these materials onto beads is paramount for industrial processes. Hence, it was reported a scalable, bio aqueous solution-based preparation strategy for Bio Zr-MOF beads production. The composite material exposed identical reactivity under the same ambient parameters compared to powdered material in an aqueous solution. These results signify a critical procedure to an integrated strategy for organophosphates removal using bio-based MOFs, which demonstrates high potential for manufacturing applications such as continued removal of organophosphates from wastewater supplies.
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spelling pubmed-86236642021-11-27 Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water Diab, Kamal E. Salama, Eslam Hassan, Hassan Shokry El-moneim, Ahmed Abd Elkady, Marwa F. Polymers (Basel) Article Organophosphate-based pesticides, such as diazinon, are among the most toxic organic contaminants to human and environment. Effective removal of diazinon from contaminated water sources is critical. Zirconium Metal−organic frameworks (Zr-MOFs) are promising candidates for the removal of organic contaminants from wastewater. Herein, we report the adequacy of a bio based Zr-MOF named MIP-202 for the removal of diazinon from water. On the other hand, the use of these materials in powder form is not workable, the development of scalable and economical processes and integrative of these materials onto beads is paramount for industrial processes. Hence, it was reported a scalable, bio aqueous solution-based preparation strategy for Bio Zr-MOF beads production. The composite material exposed identical reactivity under the same ambient parameters compared to powdered material in an aqueous solution. These results signify a critical procedure to an integrated strategy for organophosphates removal using bio-based MOFs, which demonstrates high potential for manufacturing applications such as continued removal of organophosphates from wastewater supplies. MDPI 2021-11-09 /pmc/articles/PMC8623664/ /pubmed/34833167 http://dx.doi.org/10.3390/polym13223869 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Diab, Kamal E.
Salama, Eslam
Hassan, Hassan Shokry
El-moneim, Ahmed Abd
Elkady, Marwa F.
Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
title Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
title_full Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
title_fullStr Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
title_full_unstemmed Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
title_short Bio-Zirconium Metal–Organic Framework Regenerable Bio-Beads for the Effective Removal of Organophosphates from Polluted Water
title_sort bio-zirconium metal–organic framework regenerable bio-beads for the effective removal of organophosphates from polluted water
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8623664/
https://www.ncbi.nlm.nih.gov/pubmed/34833167
http://dx.doi.org/10.3390/polym13223869
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