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Conversion of Waste Polyethylene Terephthalate (PET) Polymer into Activated Carbon and Its Feasibility to Produce Green Fuel

In this study, a novel idea was proposed to convert the polyethylene terephthalate (PET) waste drinking-water bottles into activated carbon (AC) to use for waste cooking oil (WCO) and palm fatty acid distillate (PFAD) feasibility to convert into esters. The acidic and basic char were prepared by usi...

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Autores principales: Ahangar, Firdous Ahmad, Rashid, Umer, Ahmad, Junaid, Tsubota, Toshiki, Alsalme, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8625594/
https://www.ncbi.nlm.nih.gov/pubmed/34833251
http://dx.doi.org/10.3390/polym13223952
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author Ahangar, Firdous Ahmad
Rashid, Umer
Ahmad, Junaid
Tsubota, Toshiki
Alsalme, Ali
author_facet Ahangar, Firdous Ahmad
Rashid, Umer
Ahmad, Junaid
Tsubota, Toshiki
Alsalme, Ali
author_sort Ahangar, Firdous Ahmad
collection PubMed
description In this study, a novel idea was proposed to convert the polyethylene terephthalate (PET) waste drinking-water bottles into activated carbon (AC) to use for waste cooking oil (WCO) and palm fatty acid distillate (PFAD) feasibility to convert into esters. The acidic and basic char were prepared by using the waste PET bottles. The physiochemical properties were determined by employing various analytical techniques, such as field emission scanning electron microscopy (FESEM), thermogravimetric analysis (TGA), Fourier transform infrared (FTIR), Brunauer–Emmett–Teller (BET) and temperature-programmed desorption – ammonia/carbon dioxide (TPD-NH(3)/CO(2)). The prepared PET H(3)PO(4) and PET KOH showed the higher surface area, thus illustrating that the surface of both materials has enough space for impregnation of foreign precursors. The TPD-NH(3) and TPD-CO(2) results depicted that PET H(3)PO(4) is found to have higher acidity, i.e., 18.17 mmolg(−1), due to the attachment of phosponyl groups to it during pretreatment, whereas, in the case of PET KOH, the basicity increases to 13.49 mmolg(−1). The conversion results show that prepared materials can be used as a support for an acidic and basic catalyst for the conversion of WCO and PFAD into green fuel.
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spelling pubmed-86255942021-11-27 Conversion of Waste Polyethylene Terephthalate (PET) Polymer into Activated Carbon and Its Feasibility to Produce Green Fuel Ahangar, Firdous Ahmad Rashid, Umer Ahmad, Junaid Tsubota, Toshiki Alsalme, Ali Polymers (Basel) Article In this study, a novel idea was proposed to convert the polyethylene terephthalate (PET) waste drinking-water bottles into activated carbon (AC) to use for waste cooking oil (WCO) and palm fatty acid distillate (PFAD) feasibility to convert into esters. The acidic and basic char were prepared by using the waste PET bottles. The physiochemical properties were determined by employing various analytical techniques, such as field emission scanning electron microscopy (FESEM), thermogravimetric analysis (TGA), Fourier transform infrared (FTIR), Brunauer–Emmett–Teller (BET) and temperature-programmed desorption – ammonia/carbon dioxide (TPD-NH(3)/CO(2)). The prepared PET H(3)PO(4) and PET KOH showed the higher surface area, thus illustrating that the surface of both materials has enough space for impregnation of foreign precursors. The TPD-NH(3) and TPD-CO(2) results depicted that PET H(3)PO(4) is found to have higher acidity, i.e., 18.17 mmolg(−1), due to the attachment of phosponyl groups to it during pretreatment, whereas, in the case of PET KOH, the basicity increases to 13.49 mmolg(−1). The conversion results show that prepared materials can be used as a support for an acidic and basic catalyst for the conversion of WCO and PFAD into green fuel. MDPI 2021-11-16 /pmc/articles/PMC8625594/ /pubmed/34833251 http://dx.doi.org/10.3390/polym13223952 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ahangar, Firdous Ahmad
Rashid, Umer
Ahmad, Junaid
Tsubota, Toshiki
Alsalme, Ali
Conversion of Waste Polyethylene Terephthalate (PET) Polymer into Activated Carbon and Its Feasibility to Produce Green Fuel
title Conversion of Waste Polyethylene Terephthalate (PET) Polymer into Activated Carbon and Its Feasibility to Produce Green Fuel
title_full Conversion of Waste Polyethylene Terephthalate (PET) Polymer into Activated Carbon and Its Feasibility to Produce Green Fuel
title_fullStr Conversion of Waste Polyethylene Terephthalate (PET) Polymer into Activated Carbon and Its Feasibility to Produce Green Fuel
title_full_unstemmed Conversion of Waste Polyethylene Terephthalate (PET) Polymer into Activated Carbon and Its Feasibility to Produce Green Fuel
title_short Conversion of Waste Polyethylene Terephthalate (PET) Polymer into Activated Carbon and Its Feasibility to Produce Green Fuel
title_sort conversion of waste polyethylene terephthalate (pet) polymer into activated carbon and its feasibility to produce green fuel
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8625594/
https://www.ncbi.nlm.nih.gov/pubmed/34833251
http://dx.doi.org/10.3390/polym13223952
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