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Constructing Cellulose Diacetate Aerogels with Pearl-Necklace-like Skeleton Networking Structure

Cellulose and its derivative aerogels have attracted much attention due to their renewable and biodegradable properties. However, the significant shrinkage in the supercritical drying process causes the relatively high thermal conductivity and low mechanical property of cellulose and its derivatives...

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Detalles Bibliográficos
Autores principales: Xiong, Shixian, Hu, Yangbiao, Zhang, Sizhao, Xiao, Yunyun, Li, Zhengquan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8628716/
https://www.ncbi.nlm.nih.gov/pubmed/34842720
http://dx.doi.org/10.3390/gels7040210
Descripción
Sumario:Cellulose and its derivative aerogels have attracted much attention due to their renewable and biodegradable properties. However, the significant shrinkage in the supercritical drying process causes the relatively high thermal conductivity and low mechanical property of cellulose and its derivatives aerogels. Considering the pearl-necklace-like skeleton network of silica aerogels, which can improve thermal insulation property and mechanical property. Herein, we propose a new strategy for fabricating cellulose diacetate aerogels (CDAAs) with pearl-necklace-like skeletons by using tert-butanol (TBA) as exchange solvent after experiencing the freezing-drying course. CDAAs obtained have the low density of 0.09 g cm(−3), the nanopore size in the range of 10–40 nm, the low thermal conductivity of 0.024 W m(−1) K(−1) at ambient conditions, and the excellent mechanical properties (0.18 MPa at 3% strain, 0.38 MPa at 5% strain). Ultimately, CDAAs with moderate mechanical property paralleled to cellulose-derived aerogels obtained from supercritical drying process are produced, only simultaneously owning the radial shrinkage of 6.2%. The facile method for fabricating CDAAs could provide a new reference for constructing cellulose/cellulose-derived aerogels and other biomass aerogels.