Ga–Ni supported catalytically active liquid metal solutions (SCALMS) for selective ethylene oligomerization

Non-precious metal supported catalytically active liquid metal solutions exhibit attractive performance in ethylene oligomerization. It is found for the Ga–Ni system on silica that the performance depends strongly on the applied Ga/Ni ratio. Ga-rich systems forming liquid alloys exhibit a far higher...

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Detalles Bibliográficos
Autores principales: Søgaard, Alexander, de Oliveira, Ana Luíza, Taccardi, Nicola, Haumann, Marco, Wasserscheid, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8630613/
https://www.ncbi.nlm.nih.gov/pubmed/34912539
http://dx.doi.org/10.1039/d1cy01146d
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author Søgaard, Alexander
de Oliveira, Ana Luíza
Taccardi, Nicola
Haumann, Marco
Wasserscheid, Peter
author_facet Søgaard, Alexander
de Oliveira, Ana Luíza
Taccardi, Nicola
Haumann, Marco
Wasserscheid, Peter
author_sort Søgaard, Alexander
collection PubMed
description Non-precious metal supported catalytically active liquid metal solutions exhibit attractive performance in ethylene oligomerization. It is found for the Ga–Ni system on silica that the performance depends strongly on the applied Ga/Ni ratio. Ga-rich systems forming liquid alloys exhibit a far higher Ni-based catalytic activity than solid intermetallic compounds or Ni nanoparticles.
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spelling pubmed-86306132021-12-13 Ga–Ni supported catalytically active liquid metal solutions (SCALMS) for selective ethylene oligomerization Søgaard, Alexander de Oliveira, Ana Luíza Taccardi, Nicola Haumann, Marco Wasserscheid, Peter Catal Sci Technol Chemistry Non-precious metal supported catalytically active liquid metal solutions exhibit attractive performance in ethylene oligomerization. It is found for the Ga–Ni system on silica that the performance depends strongly on the applied Ga/Ni ratio. Ga-rich systems forming liquid alloys exhibit a far higher Ni-based catalytic activity than solid intermetallic compounds or Ni nanoparticles. The Royal Society of Chemistry 2021-11-15 /pmc/articles/PMC8630613/ /pubmed/34912539 http://dx.doi.org/10.1039/d1cy01146d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Søgaard, Alexander
de Oliveira, Ana Luíza
Taccardi, Nicola
Haumann, Marco
Wasserscheid, Peter
Ga–Ni supported catalytically active liquid metal solutions (SCALMS) for selective ethylene oligomerization
title Ga–Ni supported catalytically active liquid metal solutions (SCALMS) for selective ethylene oligomerization
title_full Ga–Ni supported catalytically active liquid metal solutions (SCALMS) for selective ethylene oligomerization
title_fullStr Ga–Ni supported catalytically active liquid metal solutions (SCALMS) for selective ethylene oligomerization
title_full_unstemmed Ga–Ni supported catalytically active liquid metal solutions (SCALMS) for selective ethylene oligomerization
title_short Ga–Ni supported catalytically active liquid metal solutions (SCALMS) for selective ethylene oligomerization
title_sort ga–ni supported catalytically active liquid metal solutions (scalms) for selective ethylene oligomerization
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8630613/
https://www.ncbi.nlm.nih.gov/pubmed/34912539
http://dx.doi.org/10.1039/d1cy01146d
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AT taccardinicola ganisupportedcatalyticallyactiveliquidmetalsolutionsscalmsforselectiveethyleneoligomerization
AT haumannmarco ganisupportedcatalyticallyactiveliquidmetalsolutionsscalmsforselectiveethyleneoligomerization
AT wasserscheidpeter ganisupportedcatalyticallyactiveliquidmetalsolutionsscalmsforselectiveethyleneoligomerization

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