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High-Density Polyethylene Waste (HDPE)-Waste-Modified Lube Oil Nanocomposites as Pour Point Depressants

[Image: see text] Sustainability metrics have been established that cover the economic, social, and environmental aspects of human activities. Reduce, reuse, and recycle (3R) strategy targets solid waste management in the waste generation sectors. The purpose of this work is to study the possibility...

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Autores principales: Kamal, Rasha S., Shaban, Mahmoud M., Raju, Gunasunderi, Farag, Reem K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8637951/
https://www.ncbi.nlm.nih.gov/pubmed/34870015
http://dx.doi.org/10.1021/acsomega.1c04693
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author Kamal, Rasha S.
Shaban, Mahmoud M.
Raju, Gunasunderi
Farag, Reem K.
author_facet Kamal, Rasha S.
Shaban, Mahmoud M.
Raju, Gunasunderi
Farag, Reem K.
author_sort Kamal, Rasha S.
collection PubMed
description [Image: see text] Sustainability metrics have been established that cover the economic, social, and environmental aspects of human activities. Reduce, reuse, and recycle (3R) strategy targets solid waste management in the waste generation sectors. The purpose of this work is to study the possibility of using various plastic wastes containing high-density polyethylene (HDPE) and high-density polyethylene nanoclay (PMON) as polymer additives to modify lubricating oil. The structure of these additives was elucidated by Fourier transform infrared (FTIR) spectra, and the particle size of PMON was determined by dynamic light scattering (DLS). The thermal stability of HDPE and nanoclay HDPE (PMON) was studied, which showed higher thermal stability, and these additives completed degradation above 500 °C. The performance of HDPE and nanoclay HDPE (PMON) in lubricating oil was evaluated as pour point depressants by standard ASTM methods. The results showed that the efficiency of these additives increases with the decrease in the dose of these additives and lubricating oil treated with HDPE at 0.25% dosage lowers PPT to −30 °C, while lubricating oil treated with nanoclay HDPE (PMON7) at 0.25% dosage reduces PPT to −36 °C. Photomicrographic analysis was conducted to study accumulations and modifications in the wax crystal morphology in lube oil without and with HDPE and nanoclay HDPE (PMON7). Photomicrographs revealed that wax morphology changes due to effective pour point depressants on crystal growth.
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spelling pubmed-86379512021-12-03 High-Density Polyethylene Waste (HDPE)-Waste-Modified Lube Oil Nanocomposites as Pour Point Depressants Kamal, Rasha S. Shaban, Mahmoud M. Raju, Gunasunderi Farag, Reem K. ACS Omega [Image: see text] Sustainability metrics have been established that cover the economic, social, and environmental aspects of human activities. Reduce, reuse, and recycle (3R) strategy targets solid waste management in the waste generation sectors. The purpose of this work is to study the possibility of using various plastic wastes containing high-density polyethylene (HDPE) and high-density polyethylene nanoclay (PMON) as polymer additives to modify lubricating oil. The structure of these additives was elucidated by Fourier transform infrared (FTIR) spectra, and the particle size of PMON was determined by dynamic light scattering (DLS). The thermal stability of HDPE and nanoclay HDPE (PMON) was studied, which showed higher thermal stability, and these additives completed degradation above 500 °C. The performance of HDPE and nanoclay HDPE (PMON) in lubricating oil was evaluated as pour point depressants by standard ASTM methods. The results showed that the efficiency of these additives increases with the decrease in the dose of these additives and lubricating oil treated with HDPE at 0.25% dosage lowers PPT to −30 °C, while lubricating oil treated with nanoclay HDPE (PMON7) at 0.25% dosage reduces PPT to −36 °C. Photomicrographic analysis was conducted to study accumulations and modifications in the wax crystal morphology in lube oil without and with HDPE and nanoclay HDPE (PMON7). Photomicrographs revealed that wax morphology changes due to effective pour point depressants on crystal growth. American Chemical Society 2021-11-18 /pmc/articles/PMC8637951/ /pubmed/34870015 http://dx.doi.org/10.1021/acsomega.1c04693 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Kamal, Rasha S.
Shaban, Mahmoud M.
Raju, Gunasunderi
Farag, Reem K.
High-Density Polyethylene Waste (HDPE)-Waste-Modified Lube Oil Nanocomposites as Pour Point Depressants
title High-Density Polyethylene Waste (HDPE)-Waste-Modified Lube Oil Nanocomposites as Pour Point Depressants
title_full High-Density Polyethylene Waste (HDPE)-Waste-Modified Lube Oil Nanocomposites as Pour Point Depressants
title_fullStr High-Density Polyethylene Waste (HDPE)-Waste-Modified Lube Oil Nanocomposites as Pour Point Depressants
title_full_unstemmed High-Density Polyethylene Waste (HDPE)-Waste-Modified Lube Oil Nanocomposites as Pour Point Depressants
title_short High-Density Polyethylene Waste (HDPE)-Waste-Modified Lube Oil Nanocomposites as Pour Point Depressants
title_sort high-density polyethylene waste (hdpe)-waste-modified lube oil nanocomposites as pour point depressants
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8637951/
https://www.ncbi.nlm.nih.gov/pubmed/34870015
http://dx.doi.org/10.1021/acsomega.1c04693
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