Porous Co(2)VO(4) Nanodisk as a High-Energy and Fast-Charging Anode for Lithium-Ion Batteries

High-energy–density lithium-ion batteries (LIBs) that can be safely fast-charged are desirable for electric vehicles. However, sub-optimal lithiation potential and low capacity of commonly used LIBs anode cause safety issues and low energy density. Here we hypothesize that a cobalt vanadate oxide, Co(2)VO(4), can be attractive anode material for fast-charging LIBs due to its high capacity (~ 1000 mAh g(−1)) and safe lithiation potential (~ 0.65 V vs. Li(+)/Li). The Li(+) diffusion coefficient of Co(2)VO(4) is evaluated by theoretical calculation to be as high as 3.15 × 10(–10) cm(2) s(−1), proving Co(2)VO(4) a promising anode in fast-charging LIBs. A hexagonal porous Co(2)VO(4) nanodisk (PCVO ND) structure is designed accordingly, featuring a high specific surface area of 74.57 m(2) g(−1) and numerous pores with a pore size of 14 nm. This unique structure succeeds in enhancing Li(+) and electron transfer, leading to superior fast-charging performance than current commercial anodes. As a result, the PCVO ND shows a high initial reversible capacity of 911.0 mAh g(−1) at 0.4 C, excellent fast-charging capacity (344.3 mAh g(−1) at 10 C for 1000 cycles), outstanding long-term cycling stability (only 0.024% capacity loss per cycle at 10 C for 1000 cycles), confirming the commercial feasibility of PCVO ND in fast-charging LIBs. [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40820-021-00758-5.