Tricarbocyclic core formation of tyrosine-decahydrofluorenes implies a three-enzyme cascade with XenF-mediated sigmatropic rearrangement as a prerequisite

Tyrosine-decahydrofluorene derivatives feature a fused [6.5.6] tricarbocyclic core and a 13-membered para-cyclophane ether. Herein, we identified new xenoacremones A, B, and C (1−3) from the fungal strain Xenoacremonium sinensis ML-31 and elucidated their biosynthetic pathway using gene deletion in...

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Detalles Bibliográficos
Autores principales: Liu, Zhiguo, Li, Wei, Zhang, Peng, Fan, Jie, Zhang, Fangbo, Wang, Caixia, Li, Shuming, Sun, Yi, Chen, Shilin, Yin, Wenbing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2021
Materias:
Original Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8642415/
https://www.ncbi.nlm.nih.gov/pubmed/34900544
http://dx.doi.org/10.1016/j.apsb.2021.03.034

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8642415/
https://www.ncbi.nlm.nih.gov/pubmed/34900544
http://dx.doi.org/10.1016/j.apsb.2021.03.034

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