Cargando…

Synthesis and crystal structure of racemic (R*,R*)-2,2′-(1,4-phenyl­ene)bis­(3-phenyl-2,3,5,6-tetra­hydro-4H-1,3-thia­zin-4-one)

In the racemic title compound, C(26)H(24)N(2)O(2)S(2), one of the thia­zine rings shows a twisted boat conformation (Q = 0.743 Å, θ = 92.1°) and the other a half-chair puckering (Q = 0.669 Å, θ = 54.3°). The terminal phenyl rings are almost parallel to each other [dihedral angle 21.71 (10)°]. Both o...

Descripción completa

Detalles Bibliográficos
Autores principales: Yennawar, Hemant P., Medica, Joseph J., Silverberg, Lee J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647733/
https://www.ncbi.nlm.nih.gov/pubmed/34925894
http://dx.doi.org/10.1107/S2056989021011592
Descripción
Sumario:In the racemic title compound, C(26)H(24)N(2)O(2)S(2), one of the thia­zine rings shows a twisted boat conformation (Q = 0.743 Å, θ = 92.1°) and the other a half-chair puckering (Q = 0.669 Å, θ = 54.3°). The terminal phenyl rings are almost parallel to each other [dihedral angle 21.71 (10)°]. Both of these rings are orthogonal to the central phenyl ring, subtending a dihedral angle of about 78° in each case. The extended structure is consolidated by C—H⋯O and C—H⋯S hydrogen bonds as well as aromatic ring inter­actions of parallel-displaced and T-type. The mol­ecule has approximate C2 local symmetry but this is not carried over to its three-dimensional structure or the inter­molecular inter­actions.