Cargando…
The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride
The title complex, systematic name catena-poly[[[acetatochloridozinc(II)]-μ-(5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro[1,2,4]triazolo[1,5-a]pyrimidin-6-amine] monohydrate], {[Zn(C(2)H(3)O(2))Cl(C(15)H(15)N(5)O)]·H(2)O}( n ), is the first coordination complex in which the neutral tet...
Autores principales: | , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647737/ https://www.ncbi.nlm.nih.gov/pubmed/34925907 http://dx.doi.org/10.1107/S2056989021012226 |
_version_ | 1784610660425924608 |
---|---|
author | Shyshkina, Mariia O. Shishkina, Svitlana V Ostras, Konstantin S. Gorobets, Nikolay Yu. Chebanov, Valentyn A. Desenko, Sergey M. |
author_facet | Shyshkina, Mariia O. Shishkina, Svitlana V Ostras, Konstantin S. Gorobets, Nikolay Yu. Chebanov, Valentyn A. Desenko, Sergey M. |
author_sort | Shyshkina, Mariia O. |
collection | PubMed |
description | The title complex, systematic name catena-poly[[[acetatochloridozinc(II)]-μ-(5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro[1,2,4]triazolo[1,5-a]pyrimidin-6-amine] monohydrate], {[Zn(C(2)H(3)O(2))Cl(C(15)H(15)N(5)O)]·H(2)O}( n ), is the first coordination complex in which the neutral tetrahydrotriazolopyrimidine derivative acts as bridging ligand between two zinc molecules. As a result, polymeric chains of the coordination complex are found. The coordination of the zinc metal atom occurs with the lone pairs of the triazolo nitrogen atom and amino group. The positive charge of the zinc atom is compensated by the chlorine anion and deprotonated acetic acid. The coordination complex exists as a monohydrate in the crystalline phase. The water molecules bind neighbouring polymeric chains by the formation of O—H⋯O, O—H⋯Cl and N—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-8647737 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-86477372021-12-16 The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride Shyshkina, Mariia O. Shishkina, Svitlana V Ostras, Konstantin S. Gorobets, Nikolay Yu. Chebanov, Valentyn A. Desenko, Sergey M. Acta Crystallogr E Crystallogr Commun Research Communications The title complex, systematic name catena-poly[[[acetatochloridozinc(II)]-μ-(5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro[1,2,4]triazolo[1,5-a]pyrimidin-6-amine] monohydrate], {[Zn(C(2)H(3)O(2))Cl(C(15)H(15)N(5)O)]·H(2)O}( n ), is the first coordination complex in which the neutral tetrahydrotriazolopyrimidine derivative acts as bridging ligand between two zinc molecules. As a result, polymeric chains of the coordination complex are found. The coordination of the zinc metal atom occurs with the lone pairs of the triazolo nitrogen atom and amino group. The positive charge of the zinc atom is compensated by the chlorine anion and deprotonated acetic acid. The coordination complex exists as a monohydrate in the crystalline phase. The water molecules bind neighbouring polymeric chains by the formation of O—H⋯O, O—H⋯Cl and N—H⋯O hydrogen bonds. International Union of Crystallography 2021-11-23 /pmc/articles/PMC8647737/ /pubmed/34925907 http://dx.doi.org/10.1107/S2056989021012226 Text en © Shyshkina et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Shyshkina, Mariia O. Shishkina, Svitlana V Ostras, Konstantin S. Gorobets, Nikolay Yu. Chebanov, Valentyn A. Desenko, Sergey M. The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride |
title | The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride |
title_full | The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride |
title_fullStr | The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride |
title_full_unstemmed | The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride |
title_short | The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride |
title_sort | first coordination complex of (5r,6r,7s)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetrahydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(ii) acetate-chloride |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647737/ https://www.ncbi.nlm.nih.gov/pubmed/34925907 http://dx.doi.org/10.1107/S2056989021012226 |
work_keys_str_mv | AT shyshkinamariiao thefirstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride AT shishkinasvitlanav thefirstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride AT ostraskonstantins thefirstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride AT gorobetsnikolayyu thefirstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride AT chebanovvalentyna thefirstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride AT desenkosergeym thefirstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride AT shyshkinamariiao firstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride AT shishkinasvitlanav firstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride AT ostraskonstantins firstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride AT gorobetsnikolayyu firstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride AT chebanovvalentyna firstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride AT desenkosergeym firstcoordinationcomplexof5r6r7s5furan2yl7phenyl4567tetrahydro124triazolo15apyrimidin6aminewithzinciiacetatechloride |