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The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride

The title complex, systematic name catena-poly[[[acetato­chlorido­zinc(II)]-μ-(5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro­[1,2,4]triazolo[1,5-a]py­rimi­din-6-amine] monohydrate], {[Zn(C(2)H(3)O(2))Cl(C(15)H(15)N(5)O)]·H(2)O}( n ), is the first coordination complex in which the neutral tet...

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Autores principales: Shyshkina, Mariia O., Shishkina, Svitlana V, Ostras, Konstantin S., Gorobets, Nikolay Yu., Chebanov, Valentyn A., Desenko, Sergey M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647737/
https://www.ncbi.nlm.nih.gov/pubmed/34925907
http://dx.doi.org/10.1107/S2056989021012226
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author Shyshkina, Mariia O.
Shishkina, Svitlana V
Ostras, Konstantin S.
Gorobets, Nikolay Yu.
Chebanov, Valentyn A.
Desenko, Sergey M.
author_facet Shyshkina, Mariia O.
Shishkina, Svitlana V
Ostras, Konstantin S.
Gorobets, Nikolay Yu.
Chebanov, Valentyn A.
Desenko, Sergey M.
author_sort Shyshkina, Mariia O.
collection PubMed
description The title complex, systematic name catena-poly[[[acetato­chlorido­zinc(II)]-μ-(5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro­[1,2,4]triazolo[1,5-a]py­rimi­din-6-amine] monohydrate], {[Zn(C(2)H(3)O(2))Cl(C(15)H(15)N(5)O)]·H(2)O}( n ), is the first coordination complex in which the neutral tetra­hydro­triazolo­pyrimidine derivative acts as bridging ligand between two zinc mol­ecules. As a result, polymeric chains of the coordination complex are found. The coordination of the zinc metal atom occurs with the lone pairs of the triazolo nitro­gen atom and amino group. The positive charge of the zinc atom is compensated by the chlorine anion and deprotonated acetic acid. The coordination complex exists as a monohydrate in the crystalline phase. The water mol­ecules bind neighbouring polymeric chains by the formation of O—H⋯O, O—H⋯Cl and N—H⋯O hydrogen bonds.
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spelling pubmed-86477372021-12-16 The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride Shyshkina, Mariia O. Shishkina, Svitlana V Ostras, Konstantin S. Gorobets, Nikolay Yu. Chebanov, Valentyn A. Desenko, Sergey M. Acta Crystallogr E Crystallogr Commun Research Communications The title complex, systematic name catena-poly[[[acetato­chlorido­zinc(II)]-μ-(5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro­[1,2,4]triazolo[1,5-a]py­rimi­din-6-amine] monohydrate], {[Zn(C(2)H(3)O(2))Cl(C(15)H(15)N(5)O)]·H(2)O}( n ), is the first coordination complex in which the neutral tetra­hydro­triazolo­pyrimidine derivative acts as bridging ligand between two zinc mol­ecules. As a result, polymeric chains of the coordination complex are found. The coordination of the zinc metal atom occurs with the lone pairs of the triazolo nitro­gen atom and amino group. The positive charge of the zinc atom is compensated by the chlorine anion and deprotonated acetic acid. The coordination complex exists as a monohydrate in the crystalline phase. The water mol­ecules bind neighbouring polymeric chains by the formation of O—H⋯O, O—H⋯Cl and N—H⋯O hydrogen bonds. International Union of Crystallography 2021-11-23 /pmc/articles/PMC8647737/ /pubmed/34925907 http://dx.doi.org/10.1107/S2056989021012226 Text en © Shyshkina et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shyshkina, Mariia O.
Shishkina, Svitlana V
Ostras, Konstantin S.
Gorobets, Nikolay Yu.
Chebanov, Valentyn A.
Desenko, Sergey M.
The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride
title The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride
title_full The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride
title_fullStr The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride
title_full_unstemmed The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride
title_short The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride
title_sort first coordination complex of (5r,6r,7s)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra­hydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(ii) acetate-chloride
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647737/
https://www.ncbi.nlm.nih.gov/pubmed/34925907
http://dx.doi.org/10.1107/S2056989021012226
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