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Crystal structure and Hirshfeld surface analysis of 3-[2-(3,5-di­methyl­phen­yl)hydrazinyl­idene]benzo­furan-2(3H)-one

In the title compound, C(16)H(14)N(2)O(2), the 2,3-di­hydro-1-benzo­furan ring system is essentially planar and makes a dihedral angle of 3.69 (7)° with the di­methyl­phenyl ring. The mol­ecular conformation is stabilized by an intra­molecular N—H⋯O hydrogen bond with an S(6) ring motif. In the crys...

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Detalles Bibliográficos
Autores principales: Atioğlu, Zeliha, Akkurt, Mehmet, Shikhaliyev, Namiq Q., Askerova, Ulviyya F., Mukhtarova, Sevinc H., Askerov, Rizvan K., Bhattarai, Ajaya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647749/
https://www.ncbi.nlm.nih.gov/pubmed/34925898
http://dx.doi.org/10.1107/S2056989021011749
Descripción
Sumario:In the title compound, C(16)H(14)N(2)O(2), the 2,3-di­hydro-1-benzo­furan ring system is essentially planar and makes a dihedral angle of 3.69 (7)° with the di­methyl­phenyl ring. The mol­ecular conformation is stabilized by an intra­molecular N—H⋯O hydrogen bond with an S(6) ring motif. In the crystal, mol­ecules are connected by C—H⋯π and π–π stacking inter­actions, forming a layer lying parallel to the (11 [Image: see text] ) plane. One methyl group is disordered over two orientations, with occupancies of 0.67 (4) and 0.33 (4). Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H⋯H (51.2%), O⋯H/H⋯O (17.9%), C⋯H/H⋯C (15.2%) and C⋯C (8.1%) contacts.