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Crystal structure of 9-amino­acridinium chloride N,N-di­methyl­formamide monosolvate

9-Amino­acridinium chloride N,N-di­methyl­formamide monosolvate, C(13)H(11)N(2) (+)Cl(−)·C(3)H(7)NO, crystallizes in the monoclinic space group P2(1)/c. The salt was crystallized from N,N-di­methyl­formamide. The asymmetric unit consists of two C(13)H(11)N(2) (+)Cl(−) formula units. The 9-amino­acri...

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Detalles Bibliográficos
Autores principales: Fritsky, Igor O., Sirenko, Valerii Y., Shova, Sergiu, Kucheriv, Olesia I., Gural’skiy, Il’ya A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647755/
https://www.ncbi.nlm.nih.gov/pubmed/34925903
http://dx.doi.org/10.1107/S2056989021011816
Descripción
Sumario:9-Amino­acridinium chloride N,N-di­methyl­formamide monosolvate, C(13)H(11)N(2) (+)Cl(−)·C(3)H(7)NO, crystallizes in the monoclinic space group P2(1)/c. The salt was crystallized from N,N-di­methyl­formamide. The asymmetric unit consists of two C(13)H(11)N(2) (+)Cl(−) formula units. The 9-amino­acridinium (9-AA) mol­ecules are protonated with the proton on the N atom of the central ring. This N atom is connected to an N,N-di­methyl­formamide mol­ecule by a hydrogen bond. The H atoms of the amino groups create short contacts with two chloride ions. The 9-AA cations in adjacent layers are oriented in an anti­parallel manner. The mol­ecules are linked via a network of multidirectional π–π inter­actions between the 9-AA rings, and the whole lattice is additionally stabilized by electrostatic inter­actions between ions.