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Crystal structure of 9-aminoacridinium chloride N,N-dimethylformamide monosolvate
9-Aminoacridinium chloride N,N-dimethylformamide monosolvate, C(13)H(11)N(2) (+)Cl(−)·C(3)H(7)NO, crystallizes in the monoclinic space group P2(1)/c. The salt was crystallized from N,N-dimethylformamide. The asymmetric unit consists of two C(13)H(11)N(2) (+)Cl(−) formula units. The 9-aminoacri...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647755/ https://www.ncbi.nlm.nih.gov/pubmed/34925903 http://dx.doi.org/10.1107/S2056989021011816 |
Sumario: | 9-Aminoacridinium chloride N,N-dimethylformamide monosolvate, C(13)H(11)N(2) (+)Cl(−)·C(3)H(7)NO, crystallizes in the monoclinic space group P2(1)/c. The salt was crystallized from N,N-dimethylformamide. The asymmetric unit consists of two C(13)H(11)N(2) (+)Cl(−) formula units. The 9-aminoacridinium (9-AA) molecules are protonated with the proton on the N atom of the central ring. This N atom is connected to an N,N-dimethylformamide molecule by a hydrogen bond. The H atoms of the amino groups create short contacts with two chloride ions. The 9-AA cations in adjacent layers are oriented in an antiparallel manner. The molecules are linked via a network of multidirectional π–π interactions between the 9-AA rings, and the whole lattice is additionally stabilized by electrostatic interactions between ions. |
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