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Crystal structure of 9-amino­acridinium chloride N,N-di­methyl­formamide monosolvate

9-Amino­acridinium chloride N,N-di­methyl­formamide monosolvate, C(13)H(11)N(2) (+)Cl(−)·C(3)H(7)NO, crystallizes in the monoclinic space group P2(1)/c. The salt was crystallized from N,N-di­methyl­formamide. The asymmetric unit consists of two C(13)H(11)N(2) (+)Cl(−) formula units. The 9-amino­acri...

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Autores principales: Fritsky, Igor O., Sirenko, Valerii Y., Shova, Sergiu, Kucheriv, Olesia I., Gural’skiy, Il’ya A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647755/
https://www.ncbi.nlm.nih.gov/pubmed/34925903
http://dx.doi.org/10.1107/S2056989021011816
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author Fritsky, Igor O.
Sirenko, Valerii Y.
Shova, Sergiu
Kucheriv, Olesia I.
Gural’skiy, Il’ya A.
author_facet Fritsky, Igor O.
Sirenko, Valerii Y.
Shova, Sergiu
Kucheriv, Olesia I.
Gural’skiy, Il’ya A.
author_sort Fritsky, Igor O.
collection PubMed
description 9-Amino­acridinium chloride N,N-di­methyl­formamide monosolvate, C(13)H(11)N(2) (+)Cl(−)·C(3)H(7)NO, crystallizes in the monoclinic space group P2(1)/c. The salt was crystallized from N,N-di­methyl­formamide. The asymmetric unit consists of two C(13)H(11)N(2) (+)Cl(−) formula units. The 9-amino­acridinium (9-AA) mol­ecules are protonated with the proton on the N atom of the central ring. This N atom is connected to an N,N-di­methyl­formamide mol­ecule by a hydrogen bond. The H atoms of the amino groups create short contacts with two chloride ions. The 9-AA cations in adjacent layers are oriented in an anti­parallel manner. The mol­ecules are linked via a network of multidirectional π–π inter­actions between the 9-AA rings, and the whole lattice is additionally stabilized by electrostatic inter­actions between ions.
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spelling pubmed-86477552021-12-16 Crystal structure of 9-amino­acridinium chloride N,N-di­methyl­formamide monosolvate Fritsky, Igor O. Sirenko, Valerii Y. Shova, Sergiu Kucheriv, Olesia I. Gural’skiy, Il’ya A. Acta Crystallogr E Crystallogr Commun Research Communications 9-Amino­acridinium chloride N,N-di­methyl­formamide monosolvate, C(13)H(11)N(2) (+)Cl(−)·C(3)H(7)NO, crystallizes in the monoclinic space group P2(1)/c. The salt was crystallized from N,N-di­methyl­formamide. The asymmetric unit consists of two C(13)H(11)N(2) (+)Cl(−) formula units. The 9-amino­acridinium (9-AA) mol­ecules are protonated with the proton on the N atom of the central ring. This N atom is connected to an N,N-di­methyl­formamide mol­ecule by a hydrogen bond. The H atoms of the amino groups create short contacts with two chloride ions. The 9-AA cations in adjacent layers are oriented in an anti­parallel manner. The mol­ecules are linked via a network of multidirectional π–π inter­actions between the 9-AA rings, and the whole lattice is additionally stabilized by electrostatic inter­actions between ions. International Union of Crystallography 2021-11-16 /pmc/articles/PMC8647755/ /pubmed/34925903 http://dx.doi.org/10.1107/S2056989021011816 Text en © Fritsky et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Fritsky, Igor O.
Sirenko, Valerii Y.
Shova, Sergiu
Kucheriv, Olesia I.
Gural’skiy, Il’ya A.
Crystal structure of 9-amino­acridinium chloride N,N-di­methyl­formamide monosolvate
title Crystal structure of 9-amino­acridinium chloride N,N-di­methyl­formamide monosolvate
title_full Crystal structure of 9-amino­acridinium chloride N,N-di­methyl­formamide monosolvate
title_fullStr Crystal structure of 9-amino­acridinium chloride N,N-di­methyl­formamide monosolvate
title_full_unstemmed Crystal structure of 9-amino­acridinium chloride N,N-di­methyl­formamide monosolvate
title_short Crystal structure of 9-amino­acridinium chloride N,N-di­methyl­formamide monosolvate
title_sort crystal structure of 9-amino­acridinium chloride n,n-di­methyl­formamide monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647755/
https://www.ncbi.nlm.nih.gov/pubmed/34925903
http://dx.doi.org/10.1107/S2056989021011816
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