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Crystal structure of 9-aminoacridinium chloride N,N-dimethylformamide monosolvate
9-Aminoacridinium chloride N,N-dimethylformamide monosolvate, C(13)H(11)N(2) (+)Cl(−)·C(3)H(7)NO, crystallizes in the monoclinic space group P2(1)/c. The salt was crystallized from N,N-dimethylformamide. The asymmetric unit consists of two C(13)H(11)N(2) (+)Cl(−) formula units. The 9-aminoacri...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647755/ https://www.ncbi.nlm.nih.gov/pubmed/34925903 http://dx.doi.org/10.1107/S2056989021011816 |
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author | Fritsky, Igor O. Sirenko, Valerii Y. Shova, Sergiu Kucheriv, Olesia I. Gural’skiy, Il’ya A. |
author_facet | Fritsky, Igor O. Sirenko, Valerii Y. Shova, Sergiu Kucheriv, Olesia I. Gural’skiy, Il’ya A. |
author_sort | Fritsky, Igor O. |
collection | PubMed |
description | 9-Aminoacridinium chloride N,N-dimethylformamide monosolvate, C(13)H(11)N(2) (+)Cl(−)·C(3)H(7)NO, crystallizes in the monoclinic space group P2(1)/c. The salt was crystallized from N,N-dimethylformamide. The asymmetric unit consists of two C(13)H(11)N(2) (+)Cl(−) formula units. The 9-aminoacridinium (9-AA) molecules are protonated with the proton on the N atom of the central ring. This N atom is connected to an N,N-dimethylformamide molecule by a hydrogen bond. The H atoms of the amino groups create short contacts with two chloride ions. The 9-AA cations in adjacent layers are oriented in an antiparallel manner. The molecules are linked via a network of multidirectional π–π interactions between the 9-AA rings, and the whole lattice is additionally stabilized by electrostatic interactions between ions. |
format | Online Article Text |
id | pubmed-8647755 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-86477552021-12-16 Crystal structure of 9-aminoacridinium chloride N,N-dimethylformamide monosolvate Fritsky, Igor O. Sirenko, Valerii Y. Shova, Sergiu Kucheriv, Olesia I. Gural’skiy, Il’ya A. Acta Crystallogr E Crystallogr Commun Research Communications 9-Aminoacridinium chloride N,N-dimethylformamide monosolvate, C(13)H(11)N(2) (+)Cl(−)·C(3)H(7)NO, crystallizes in the monoclinic space group P2(1)/c. The salt was crystallized from N,N-dimethylformamide. The asymmetric unit consists of two C(13)H(11)N(2) (+)Cl(−) formula units. The 9-aminoacridinium (9-AA) molecules are protonated with the proton on the N atom of the central ring. This N atom is connected to an N,N-dimethylformamide molecule by a hydrogen bond. The H atoms of the amino groups create short contacts with two chloride ions. The 9-AA cations in adjacent layers are oriented in an antiparallel manner. The molecules are linked via a network of multidirectional π–π interactions between the 9-AA rings, and the whole lattice is additionally stabilized by electrostatic interactions between ions. International Union of Crystallography 2021-11-16 /pmc/articles/PMC8647755/ /pubmed/34925903 http://dx.doi.org/10.1107/S2056989021011816 Text en © Fritsky et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Fritsky, Igor O. Sirenko, Valerii Y. Shova, Sergiu Kucheriv, Olesia I. Gural’skiy, Il’ya A. Crystal structure of 9-aminoacridinium chloride N,N-dimethylformamide monosolvate |
title | Crystal structure of 9-aminoacridinium chloride N,N-dimethylformamide monosolvate |
title_full | Crystal structure of 9-aminoacridinium chloride N,N-dimethylformamide monosolvate |
title_fullStr | Crystal structure of 9-aminoacridinium chloride N,N-dimethylformamide monosolvate |
title_full_unstemmed | Crystal structure of 9-aminoacridinium chloride N,N-dimethylformamide monosolvate |
title_short | Crystal structure of 9-aminoacridinium chloride N,N-dimethylformamide monosolvate |
title_sort | crystal structure of 9-aminoacridinium chloride n,n-dimethylformamide monosolvate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647755/ https://www.ncbi.nlm.nih.gov/pubmed/34925903 http://dx.doi.org/10.1107/S2056989021011816 |
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