Crystal structure of 1,1′-(pyridine-2,6-di­yl)bis­[N-(pyridin-2-ylmeth­yl)methanaminium] dichloride dihydrate

In the title compound, C(19)H(23)N(5) (2+)·2Cl(−)·2H(2)O, the two pyridine side arms are not coplanar, with the terminal pyridine rings subtending a dihedral angle of 26.45 (6)°. In the crystal, hydrogen bonds, inter­molecular C—H⋯Cl contacts and a weak C—H⋯O inter­action connect the mol­ecule with...

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Autores principales: Merabet, Layachi, Tassé, Marine, Mallet-Ladeira, Sonia, Kaboub, Lakhemici, Malfant, Isabelle
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647756/
https://www.ncbi.nlm.nih.gov/pubmed/34925901
http://dx.doi.org/10.1107/S205698902101183X
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author Merabet, Layachi
Tassé, Marine
Mallet-Ladeira, Sonia
Kaboub, Lakhemici
Malfant, Isabelle
author_facet Merabet, Layachi
Tassé, Marine
Mallet-Ladeira, Sonia
Kaboub, Lakhemici
Malfant, Isabelle
author_sort Merabet, Layachi
collection PubMed
description In the title compound, C(19)H(23)N(5) (2+)·2Cl(−)·2H(2)O, the two pyridine side arms are not coplanar, with the terminal pyridine rings subtending a dihedral angle of 26.45 (6)°. In the crystal, hydrogen bonds, inter­molecular C—H⋯Cl contacts and a weak C—H⋯O inter­action connect the mol­ecule with neighbouring chloride counter-anions and lattice water mol­ecules. The crystal packing also features by π–π inter­actions with centroid-centroid distances of 3.4864 (12) and 3.5129 (13) Å.
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spelling pubmed-86477562021-12-16 Crystal structure of 1,1′-(pyridine-2,6-di­yl)bis­[N-(pyridin-2-ylmeth­yl)methanaminium] dichloride dihydrate Merabet, Layachi Tassé, Marine Mallet-Ladeira, Sonia Kaboub, Lakhemici Malfant, Isabelle Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(19)H(23)N(5) (2+)·2Cl(−)·2H(2)O, the two pyridine side arms are not coplanar, with the terminal pyridine rings subtending a dihedral angle of 26.45 (6)°. In the crystal, hydrogen bonds, inter­molecular C—H⋯Cl contacts and a weak C—H⋯O inter­action connect the mol­ecule with neighbouring chloride counter-anions and lattice water mol­ecules. The crystal packing also features by π–π inter­actions with centroid-centroid distances of 3.4864 (12) and 3.5129 (13) Å. International Union of Crystallography 2021-11-16 /pmc/articles/PMC8647756/ /pubmed/34925901 http://dx.doi.org/10.1107/S205698902101183X Text en © Merabet et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Merabet, Layachi
Tassé, Marine
Mallet-Ladeira, Sonia
Kaboub, Lakhemici
Malfant, Isabelle
Crystal structure of 1,1′-(pyridine-2,6-di­yl)bis­[N-(pyridin-2-ylmeth­yl)methanaminium] dichloride dihydrate
title Crystal structure of 1,1′-(pyridine-2,6-di­yl)bis­[N-(pyridin-2-ylmeth­yl)methanaminium] dichloride dihydrate
title_full Crystal structure of 1,1′-(pyridine-2,6-di­yl)bis­[N-(pyridin-2-ylmeth­yl)methanaminium] dichloride dihydrate
title_fullStr Crystal structure of 1,1′-(pyridine-2,6-di­yl)bis­[N-(pyridin-2-ylmeth­yl)methanaminium] dichloride dihydrate
title_full_unstemmed Crystal structure of 1,1′-(pyridine-2,6-di­yl)bis­[N-(pyridin-2-ylmeth­yl)methanaminium] dichloride dihydrate
title_short Crystal structure of 1,1′-(pyridine-2,6-di­yl)bis­[N-(pyridin-2-ylmeth­yl)methanaminium] dichloride dihydrate
title_sort crystal structure of 1,1′-(pyridine-2,6-di­yl)bis­[n-(pyridin-2-ylmeth­yl)methanaminium] dichloride dihydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647756/
https://www.ncbi.nlm.nih.gov/pubmed/34925901
http://dx.doi.org/10.1107/S205698902101183X
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