Highly Efficient Heavy Atom Free Room Temperature Phosphorescence by Host-Guest Doping

Recently, there has been remarkable progress of the host-guest doped pure organic room-temperature phosphorescence (RTP) materials. However, it remains a great challenge to develop highly efficient host-guest doping systems. In this study, we have successfully developed a heavy atom free pure organi...

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Detalles Bibliográficos
Autores principales: Cao, Jinzhu, Zhang, Meng, Singh, Manjeet, An, Zhongfu, Ji, Lingfei, Shi, Huifang, Jiang, Yijian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8649652/
https://www.ncbi.nlm.nih.gov/pubmed/34888296
http://dx.doi.org/10.3389/fchem.2021.781294
Descripción
Sumario:Recently, there has been remarkable progress of the host-guest doped pure organic room-temperature phosphorescence (RTP) materials. However, it remains a great challenge to develop highly efficient host-guest doping systems. In this study, we have successfully developed a heavy atom free pure organic molecular doped system (benzophenone-thianthrene, respectively) with efficient RTP through a simple host-guest doping strategy. Furthermore, by optimizing the doping ratios, the host-guest material with a molar ratio of 100:1 presented an efficient RTP emission with 46% quantum efficiency and a long lifetime of up to 9.17 ms under ambient conditions. This work will provide an effective way to design new organic doping systems with RTP.

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