Unique Biradical Intermediate in the Mechanism of the Heme Enzyme Chlorite Dismutase

[Image: see text] The heme enzyme chlorite dismutase (Cld) catalyzes O–O bond formation as part of the conversion of the toxic chlorite (ClO(2)(–)) to chloride (Cl(–)) and molecular oxygen (O(2)). Enzymatic O–O bond formation is rare in nature, and therefore, the reaction mechanism of Cld is of grea...

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Detalles Bibliográficos
Autores principales: Püschmann, Julia, Mahor, Durga, de Geus, Daniël C., Strampraad, Marc J. F., Srour, Batoul, Hagen, Wilfred R., Todorovic, Smilja, Hagedoorn, Peter-Leon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8650003/
https://www.ncbi.nlm.nih.gov/pubmed/34888122
http://dx.doi.org/10.1021/acscatal.1c03432

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