Ru-Catalyzed Reverse Water Gas Shift Reaction with Near-Unity Selectivity and Superior Stability

[Image: see text] Cascade catalysis of reverse water gas shift (RWGS) and well-established CO hydrogenation holds promise for the conversion of greenhouse gas CO(2) and renewable H(2) into liquid hydrocarbons and methanol under mild conditions. However, it remains a big challenge to develop low-temperature RWGS catalysts with high activity, selectivity, and stability. Here, we report the design of an efficient RWGS catalyst by encapsulating ruthenium clusters with the size of 1 nm inside hollow silica shells. The spatially confined structure prevents the sintering of Ru clusters while the permeable silica layer allows the diffusion of gaseous reactants and products. This catalyst with reduced particle sizes not only inherits the excellent activity of Ru in CO(2) hydrogenation reactions but also exhibits nearly 100% CO selectivity and superior stability at 200–500 °C. The ability to selectively produce CO from CO(2) at relatively low temperatures paves the way for the production of value-added fuels from CO(2) and renewable H(2).