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Synthesis of a heterobimetallic actinide nitride and an analysis of its bonding
Reaction of [K(DME)][Th{N(R)(SiMe(2)CH(2))}(2)(NR(2))] (R = SiMe(3)) with 1 equiv. of [U(NR(2))(3)(NH(2))] (1) in THF, in the presence of 18-crown-6, results in formation of a bridged uranium–thorium nitride complex, [K(18-crown-6)(THF)(2)][(NR(2))(3)U(IV)(μ-N)Th(IV)(NR(2))(3)] (2), which can be iso...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8653994/ https://www.ncbi.nlm.nih.gov/pubmed/35003580 http://dx.doi.org/10.1039/d1sc05072a |