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On-surface cyclodehydrogenation reaction pathway determined by selective molecular deuterations

Understanding the reaction mechanisms of dehydrogenative C(aryl)–C(aryl) coupling is the key to directed formation of π-extended polycyclic aromatic hydrocarbons. Here we utilize isotopic labeling to identify the exact pathway of cyclodehydrogenation reaction in the on-surface synthesis of model ato...

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Detalles Bibliográficos
Autores principales: Ma, Chuanxu, Xiao, Zhongcan, Bonnesen, Peter V., Liang, Liangbo, Puretzky, Alexander A., Huang, Jingsong, Kolmer, Marek, Sumpter, Bobby G., Lu, Wenchang, Hong, Kunlun, Bernholc, Jerzy, Li, An-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8653995/
https://www.ncbi.nlm.nih.gov/pubmed/35003594
http://dx.doi.org/10.1039/d1sc04908a

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