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Metal-catalyzed B–H acylmethylation of pyridylcarboranes: access to carborane-fused indoliziniums and quinoliziniums

Metal-catalyzed mono-acylmethylation of pyridylcarboranes has been realized using α-carbonyl sulfoxonium ylides as a coupling partner. The reaction features high efficiency, excellent site-selectivity and good functional group tolerance. In the presence of pyridyl and enolizable acylmethyl groups, a...

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Detalles Bibliográficos
Autores principales:	Cao, Hou-Ji, Wei, Xing, Sun, Fangxiang, Zhang, Xiaolei, Lu, Changsheng, Yan, Hong
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8654026/ https://www.ncbi.nlm.nih.gov/pubmed/35003585 http://dx.doi.org/10.1039/d1sc05296a

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