meso-Antracenyl-BODIPY Dyad as a New Photocatalyst in Atom-Transfer Radical Addition Reactions

[Image: see text] We demonstrate that because of the efficient generation of triplet excited state under UV or visible-light irradiation, meso-antracenyl-BODIPY donor–acceptor dyad can catalyze atom-transfer radical addition (ATRA) reactions between bromomalonate and alkenes. This finding paves the...

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Autores principales: Abuhadba, Sara, Tsuji, Miu, Mani, Tomoyasu, Esipova, Tatiana V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8655941/
https://www.ncbi.nlm.nih.gov/pubmed/34901630
http://dx.doi.org/10.1021/acsomega.1c04724
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author Abuhadba, Sara
Tsuji, Miu
Mani, Tomoyasu
Esipova, Tatiana V.
author_facet Abuhadba, Sara
Tsuji, Miu
Mani, Tomoyasu
Esipova, Tatiana V.
author_sort Abuhadba, Sara
collection PubMed
description [Image: see text] We demonstrate that because of the efficient generation of triplet excited state under UV or visible-light irradiation, meso-antracenyl-BODIPY donor–acceptor dyad can catalyze atom-transfer radical addition (ATRA) reactions between bromomalonate and alkenes. This finding paves the way for the design and application of the new type of heavy atom-free organic chromophores for photocatalysis.
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spelling pubmed-86559412021-12-10 meso-Antracenyl-BODIPY Dyad as a New Photocatalyst in Atom-Transfer Radical Addition Reactions Abuhadba, Sara Tsuji, Miu Mani, Tomoyasu Esipova, Tatiana V. ACS Omega [Image: see text] We demonstrate that because of the efficient generation of triplet excited state under UV or visible-light irradiation, meso-antracenyl-BODIPY donor–acceptor dyad can catalyze atom-transfer radical addition (ATRA) reactions between bromomalonate and alkenes. This finding paves the way for the design and application of the new type of heavy atom-free organic chromophores for photocatalysis. American Chemical Society 2021-11-19 /pmc/articles/PMC8655941/ /pubmed/34901630 http://dx.doi.org/10.1021/acsomega.1c04724 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Abuhadba, Sara
Tsuji, Miu
Mani, Tomoyasu
Esipova, Tatiana V.
meso-Antracenyl-BODIPY Dyad as a New Photocatalyst in Atom-Transfer Radical Addition Reactions
title meso-Antracenyl-BODIPY Dyad as a New Photocatalyst in Atom-Transfer Radical Addition Reactions
title_full meso-Antracenyl-BODIPY Dyad as a New Photocatalyst in Atom-Transfer Radical Addition Reactions
title_fullStr meso-Antracenyl-BODIPY Dyad as a New Photocatalyst in Atom-Transfer Radical Addition Reactions
title_full_unstemmed meso-Antracenyl-BODIPY Dyad as a New Photocatalyst in Atom-Transfer Radical Addition Reactions
title_short meso-Antracenyl-BODIPY Dyad as a New Photocatalyst in Atom-Transfer Radical Addition Reactions
title_sort meso-antracenyl-bodipy dyad as a new photocatalyst in atom-transfer radical addition reactions
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8655941/
https://www.ncbi.nlm.nih.gov/pubmed/34901630
http://dx.doi.org/10.1021/acsomega.1c04724
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AT manitomoyasu mesoantracenylbodipydyadasanewphotocatalystinatomtransferradicaladditionreactions
AT esipovatatianav mesoantracenylbodipydyadasanewphotocatalystinatomtransferradicaladditionreactions

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