Cargando…

Temperature-Induced Change of Water Structure in Aqueous Solutions of Some Kosmotropic and Chaotropic Salts

The hydrogen bond structure of water was examined by comparing the temperature dependent OH-stretching bands of water and aqueous NaClO(4), KClO(4), Na(2)SO(4), and K(2)SO(4) solutions. Results called attention to the role of cations on top of the importance of anions determining the emerging struct...

Descripción completa

Detalles Bibliográficos
Autores principales: Kovács, Ferenc, Yan, Hui, Li, Heng, Kunsági-Máté, Sándor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8657926/
https://www.ncbi.nlm.nih.gov/pubmed/34884702
http://dx.doi.org/10.3390/ijms222312896
_version_ 1784612612693032960
author Kovács, Ferenc
Yan, Hui
Li, Heng
Kunsági-Máté, Sándor
author_facet Kovács, Ferenc
Yan, Hui
Li, Heng
Kunsági-Máté, Sándor
author_sort Kovács, Ferenc
collection PubMed
description The hydrogen bond structure of water was examined by comparing the temperature dependent OH-stretching bands of water and aqueous NaClO(4), KClO(4), Na(2)SO(4), and K(2)SO(4) solutions. Results called attention to the role of cations on top of the importance of anions determining the emerging structure of a multi-layered system consisting single water rings or multi-ring water-clusters.
format Online
Article
Text
id pubmed-8657926
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-86579262021-12-10 Temperature-Induced Change of Water Structure in Aqueous Solutions of Some Kosmotropic and Chaotropic Salts Kovács, Ferenc Yan, Hui Li, Heng Kunsági-Máté, Sándor Int J Mol Sci Article The hydrogen bond structure of water was examined by comparing the temperature dependent OH-stretching bands of water and aqueous NaClO(4), KClO(4), Na(2)SO(4), and K(2)SO(4) solutions. Results called attention to the role of cations on top of the importance of anions determining the emerging structure of a multi-layered system consisting single water rings or multi-ring water-clusters. MDPI 2021-11-29 /pmc/articles/PMC8657926/ /pubmed/34884702 http://dx.doi.org/10.3390/ijms222312896 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Kovács, Ferenc
Yan, Hui
Li, Heng
Kunsági-Máté, Sándor
Temperature-Induced Change of Water Structure in Aqueous Solutions of Some Kosmotropic and Chaotropic Salts
title Temperature-Induced Change of Water Structure in Aqueous Solutions of Some Kosmotropic and Chaotropic Salts
title_full Temperature-Induced Change of Water Structure in Aqueous Solutions of Some Kosmotropic and Chaotropic Salts
title_fullStr Temperature-Induced Change of Water Structure in Aqueous Solutions of Some Kosmotropic and Chaotropic Salts
title_full_unstemmed Temperature-Induced Change of Water Structure in Aqueous Solutions of Some Kosmotropic and Chaotropic Salts
title_short Temperature-Induced Change of Water Structure in Aqueous Solutions of Some Kosmotropic and Chaotropic Salts
title_sort temperature-induced change of water structure in aqueous solutions of some kosmotropic and chaotropic salts
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8657926/
https://www.ncbi.nlm.nih.gov/pubmed/34884702
http://dx.doi.org/10.3390/ijms222312896
work_keys_str_mv AT kovacsferenc temperatureinducedchangeofwaterstructureinaqueoussolutionsofsomekosmotropicandchaotropicsalts
AT yanhui temperatureinducedchangeofwaterstructureinaqueoussolutionsofsomekosmotropicandchaotropicsalts
AT liheng temperatureinducedchangeofwaterstructureinaqueoussolutionsofsomekosmotropicandchaotropicsalts
AT kunsagimatesandor temperatureinducedchangeofwaterstructureinaqueoussolutionsofsomekosmotropicandchaotropicsalts