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Synthesis of a Hexameric Magnesium 4-pyridyl Complex with Cyclohexane-like Ring Structure via Reductive C-N Activation
The reaction of [{((Ar)nacnac)Mg}(2)] ((Ar)nacnac = HC{MeC(NAr)}(2), Ar = 2,6-diisopropylphenyl, Dip, or 2,6-diethylphenyl, Dep) with 4-dimethylaminopyridine (DMAP) at elevated temperatures afforded the hexameric magnesium 4-pyridyl complex [{((Ar)nacnac)Mg(4-C(5)H(4)N)}(6)] via reductive cleavage o...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8658945/ https://www.ncbi.nlm.nih.gov/pubmed/34885796 http://dx.doi.org/10.3390/molecules26237214 |