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CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models

Activated carbons with different textural characteristic were derived by the chemical activation of raw beet molasses with solid KOH, while the activation temperature was changed in the range 650 °C to 800 °C. The adsorption of CO(2) on activated carbons was investigated. Langmuir, Freundlich, Sips,...

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Detalles Bibliográficos
Autores principales: Kiełbasa, Karolina, Kamińska, Adrianna, Niedoba, Oliwier, Michalkiewicz, Beata
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659170/
https://www.ncbi.nlm.nih.gov/pubmed/34885613
http://dx.doi.org/10.3390/ma14237458
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author Kiełbasa, Karolina
Kamińska, Adrianna
Niedoba, Oliwier
Michalkiewicz, Beata
author_facet Kiełbasa, Karolina
Kamińska, Adrianna
Niedoba, Oliwier
Michalkiewicz, Beata
author_sort Kiełbasa, Karolina
collection PubMed
description Activated carbons with different textural characteristic were derived by the chemical activation of raw beet molasses with solid KOH, while the activation temperature was changed in the range 650 °C to 800 °C. The adsorption of CO(2) on activated carbons was investigated. Langmuir, Freundlich, Sips, Toth, Unilan, Fritz-Schlunder, Radke-Prausnitz, Temkin-Pyzhev, Dubinin-Radushkevich, and Jovanovich equations were selected to fit the experimental data of CO(2) adsorption. An error analysis (the sum of the squares of errors, the hybrid fractional error function, the average relative error, the Marquardt’s percent standard deviation, and the sum of the absolute errors) was conducted to examine the effect of using various error standards for the isotherm model parameter calculation. The best fit was observed to the Radke-Prausnitz model.
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spelling pubmed-86591702021-12-10 CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models Kiełbasa, Karolina Kamińska, Adrianna Niedoba, Oliwier Michalkiewicz, Beata Materials (Basel) Article Activated carbons with different textural characteristic were derived by the chemical activation of raw beet molasses with solid KOH, while the activation temperature was changed in the range 650 °C to 800 °C. The adsorption of CO(2) on activated carbons was investigated. Langmuir, Freundlich, Sips, Toth, Unilan, Fritz-Schlunder, Radke-Prausnitz, Temkin-Pyzhev, Dubinin-Radushkevich, and Jovanovich equations were selected to fit the experimental data of CO(2) adsorption. An error analysis (the sum of the squares of errors, the hybrid fractional error function, the average relative error, the Marquardt’s percent standard deviation, and the sum of the absolute errors) was conducted to examine the effect of using various error standards for the isotherm model parameter calculation. The best fit was observed to the Radke-Prausnitz model. MDPI 2021-12-05 /pmc/articles/PMC8659170/ /pubmed/34885613 http://dx.doi.org/10.3390/ma14237458 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Kiełbasa, Karolina
Kamińska, Adrianna
Niedoba, Oliwier
Michalkiewicz, Beata
CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models
title CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models
title_full CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models
title_fullStr CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models
title_full_unstemmed CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models
title_short CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models
title_sort co(2) adsorption on activated carbons prepared from molasses: a comparison of two and three parametric models
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659170/
https://www.ncbi.nlm.nih.gov/pubmed/34885613
http://dx.doi.org/10.3390/ma14237458
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