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CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models
Activated carbons with different textural characteristic were derived by the chemical activation of raw beet molasses with solid KOH, while the activation temperature was changed in the range 650 °C to 800 °C. The adsorption of CO(2) on activated carbons was investigated. Langmuir, Freundlich, Sips,...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659170/ https://www.ncbi.nlm.nih.gov/pubmed/34885613 http://dx.doi.org/10.3390/ma14237458 |
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author | Kiełbasa, Karolina Kamińska, Adrianna Niedoba, Oliwier Michalkiewicz, Beata |
author_facet | Kiełbasa, Karolina Kamińska, Adrianna Niedoba, Oliwier Michalkiewicz, Beata |
author_sort | Kiełbasa, Karolina |
collection | PubMed |
description | Activated carbons with different textural characteristic were derived by the chemical activation of raw beet molasses with solid KOH, while the activation temperature was changed in the range 650 °C to 800 °C. The adsorption of CO(2) on activated carbons was investigated. Langmuir, Freundlich, Sips, Toth, Unilan, Fritz-Schlunder, Radke-Prausnitz, Temkin-Pyzhev, Dubinin-Radushkevich, and Jovanovich equations were selected to fit the experimental data of CO(2) adsorption. An error analysis (the sum of the squares of errors, the hybrid fractional error function, the average relative error, the Marquardt’s percent standard deviation, and the sum of the absolute errors) was conducted to examine the effect of using various error standards for the isotherm model parameter calculation. The best fit was observed to the Radke-Prausnitz model. |
format | Online Article Text |
id | pubmed-8659170 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-86591702021-12-10 CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models Kiełbasa, Karolina Kamińska, Adrianna Niedoba, Oliwier Michalkiewicz, Beata Materials (Basel) Article Activated carbons with different textural characteristic were derived by the chemical activation of raw beet molasses with solid KOH, while the activation temperature was changed in the range 650 °C to 800 °C. The adsorption of CO(2) on activated carbons was investigated. Langmuir, Freundlich, Sips, Toth, Unilan, Fritz-Schlunder, Radke-Prausnitz, Temkin-Pyzhev, Dubinin-Radushkevich, and Jovanovich equations were selected to fit the experimental data of CO(2) adsorption. An error analysis (the sum of the squares of errors, the hybrid fractional error function, the average relative error, the Marquardt’s percent standard deviation, and the sum of the absolute errors) was conducted to examine the effect of using various error standards for the isotherm model parameter calculation. The best fit was observed to the Radke-Prausnitz model. MDPI 2021-12-05 /pmc/articles/PMC8659170/ /pubmed/34885613 http://dx.doi.org/10.3390/ma14237458 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Kiełbasa, Karolina Kamińska, Adrianna Niedoba, Oliwier Michalkiewicz, Beata CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models |
title | CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models |
title_full | CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models |
title_fullStr | CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models |
title_full_unstemmed | CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models |
title_short | CO(2) Adsorption on Activated Carbons Prepared from Molasses: A Comparison of Two and Three Parametric Models |
title_sort | co(2) adsorption on activated carbons prepared from molasses: a comparison of two and three parametric models |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659170/ https://www.ncbi.nlm.nih.gov/pubmed/34885613 http://dx.doi.org/10.3390/ma14237458 |
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