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One-Pot Facile Synthesis of Noble Metal Nanoparticles Supported on rGO with Enhanced Catalytic Performance for 4-Nitrophenol Reduction

In this study, reduced graphene oxide (rGO)-supported noble metal (gold, silver, and platinum) nanoparticle catalysts were prepared via the one-pot facile co-reduction technique. Various measurement techniques were used to investigate the structures and properties of the catalysts. The relative inte...

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Autores principales: Zhang, Xiaolong, Jin, Shilei, Zhang, Yuhan, Wang, Liyuan, Liu, Yang, Duan, Qian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659260/
https://www.ncbi.nlm.nih.gov/pubmed/34885841
http://dx.doi.org/10.3390/molecules26237261
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author Zhang, Xiaolong
Jin, Shilei
Zhang, Yuhan
Wang, Liyuan
Liu, Yang
Duan, Qian
author_facet Zhang, Xiaolong
Jin, Shilei
Zhang, Yuhan
Wang, Liyuan
Liu, Yang
Duan, Qian
author_sort Zhang, Xiaolong
collection PubMed
description In this study, reduced graphene oxide (rGO)-supported noble metal (gold, silver, and platinum) nanoparticle catalysts were prepared via the one-pot facile co-reduction technique. Various measurement techniques were used to investigate the structures and properties of the catalysts. The relative intensity ratios of I(D)/I(G) in rGO/Au, rGO/Ag, rGO/Pt, and GO were 1.106, 1.078, 1.047, and 0.863, respectively. The results showed the formation of rGO and that noble metal nanoparticles were decorated on rGO. Furthermore, the catalytic activities of the designed nanocomposites were investigated via 4-nitrophenol. The catalysts were used in 4-nitrophenol reduction. The catalytic performance of the catalysts was evaluated using the apparent rate constant k values. The k value of rGO/Au was 0.618 min(−1), which was higher than those of rGO/Ag (0.55 min(−1)) and rGO/Pt (0.038 min(−1)). The result proved that the rGO/Au catalyst exhibited a higher catalytic performance than the rGO/Ag catalyst and the rGO/Pt catalyst. The results provide a facile method for the synthesis of rGO-supported nanomaterials in catalysis.
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spelling pubmed-86592602021-12-10 One-Pot Facile Synthesis of Noble Metal Nanoparticles Supported on rGO with Enhanced Catalytic Performance for 4-Nitrophenol Reduction Zhang, Xiaolong Jin, Shilei Zhang, Yuhan Wang, Liyuan Liu, Yang Duan, Qian Molecules Article In this study, reduced graphene oxide (rGO)-supported noble metal (gold, silver, and platinum) nanoparticle catalysts were prepared via the one-pot facile co-reduction technique. Various measurement techniques were used to investigate the structures and properties of the catalysts. The relative intensity ratios of I(D)/I(G) in rGO/Au, rGO/Ag, rGO/Pt, and GO were 1.106, 1.078, 1.047, and 0.863, respectively. The results showed the formation of rGO and that noble metal nanoparticles were decorated on rGO. Furthermore, the catalytic activities of the designed nanocomposites were investigated via 4-nitrophenol. The catalysts were used in 4-nitrophenol reduction. The catalytic performance of the catalysts was evaluated using the apparent rate constant k values. The k value of rGO/Au was 0.618 min(−1), which was higher than those of rGO/Ag (0.55 min(−1)) and rGO/Pt (0.038 min(−1)). The result proved that the rGO/Au catalyst exhibited a higher catalytic performance than the rGO/Ag catalyst and the rGO/Pt catalyst. The results provide a facile method for the synthesis of rGO-supported nanomaterials in catalysis. MDPI 2021-11-30 /pmc/articles/PMC8659260/ /pubmed/34885841 http://dx.doi.org/10.3390/molecules26237261 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhang, Xiaolong
Jin, Shilei
Zhang, Yuhan
Wang, Liyuan
Liu, Yang
Duan, Qian
One-Pot Facile Synthesis of Noble Metal Nanoparticles Supported on rGO with Enhanced Catalytic Performance for 4-Nitrophenol Reduction
title One-Pot Facile Synthesis of Noble Metal Nanoparticles Supported on rGO with Enhanced Catalytic Performance for 4-Nitrophenol Reduction
title_full One-Pot Facile Synthesis of Noble Metal Nanoparticles Supported on rGO with Enhanced Catalytic Performance for 4-Nitrophenol Reduction
title_fullStr One-Pot Facile Synthesis of Noble Metal Nanoparticles Supported on rGO with Enhanced Catalytic Performance for 4-Nitrophenol Reduction
title_full_unstemmed One-Pot Facile Synthesis of Noble Metal Nanoparticles Supported on rGO with Enhanced Catalytic Performance for 4-Nitrophenol Reduction
title_short One-Pot Facile Synthesis of Noble Metal Nanoparticles Supported on rGO with Enhanced Catalytic Performance for 4-Nitrophenol Reduction
title_sort one-pot facile synthesis of noble metal nanoparticles supported on rgo with enhanced catalytic performance for 4-nitrophenol reduction
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659260/
https://www.ncbi.nlm.nih.gov/pubmed/34885841
http://dx.doi.org/10.3390/molecules26237261
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