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Lignocellulose-Based Superabsorbent Polymer Gel Crosslinked with Magnesium Aluminum Silicate for Highly Removal of Zn (II) from Aqueous Solution

Lignocellulose (LCE) was ultrasonically treated and intercalated into magnesium aluminum silicate (MOT) clay to prepare a nano-lignocellulose magnesium aluminum silicate polymer gel (nano-LCE-MOT) for the removal of Zn (II) from aqueous solution. The product was characterised using nitrogen adsorpti...

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Autores principales: An, Yuhong, Zhang, Wanqi, Liu, Hui, Zhong, Yuan, Hu, Zichu, Shao, Yali, Chen, Zhangjing, Ren, Yukun, Wang, Boyun, Wang, Sunguo, Zhang, Xiaotao, Wang, Ximing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659497/
https://www.ncbi.nlm.nih.gov/pubmed/34883663
http://dx.doi.org/10.3390/polym13234161
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author An, Yuhong
Zhang, Wanqi
Liu, Hui
Zhong, Yuan
Hu, Zichu
Shao, Yali
Chen, Zhangjing
Ren, Yukun
Wang, Boyun
Wang, Sunguo
Zhang, Xiaotao
Wang, Ximing
author_facet An, Yuhong
Zhang, Wanqi
Liu, Hui
Zhong, Yuan
Hu, Zichu
Shao, Yali
Chen, Zhangjing
Ren, Yukun
Wang, Boyun
Wang, Sunguo
Zhang, Xiaotao
Wang, Ximing
author_sort An, Yuhong
collection PubMed
description Lignocellulose (LCE) was ultrasonically treated and intercalated into magnesium aluminum silicate (MOT) clay to prepare a nano-lignocellulose magnesium aluminum silicate polymer gel (nano-LCE-MOT) for the removal of Zn (II) from aqueous solution. The product was characterised using nitrogen adsorption/desorption isotherm measurements, Fourier-transform infrared spectroscopy, scanning electron microscopy and energy-dispersive X-ray spectroscopy. The conditions for the adsorption of Zn (II) on nano-LCE-MOT were screened, and adsorption kinetics and isotherm model analysis were carried out to explore the adsorption mechanism and achieve the optimal adsorption of Zn (II). Optimal adsorption was achieved at an initial Zn (II) concentration of 800 mg/L at 60 °C in 160 min at a pH of 4.52. The adsorption kinetics were explored using a pseudo-second-order model, with the isotherm adsorption equilibrium found to conform to the Langmuir model. The maximum adsorption capacity of the nano-LCE-MOT polymer gel toward Zn (II) is 513.48 mg/g. The materials with adsorbed Zn (II) were desorbed using different media, with HCl found to be the most ideal medium to desorb Zn (II). The optimal desorption of Zn (II) was achieved in 0.08 mol/L HCl solution at 65 °C in 60 min. Under these conditions, Zn (II) was almost completely desorbed from the adsorbents, with the adsorption effect after cycling being slightly different from that of the initial adsorption.
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spelling pubmed-86594972021-12-10 Lignocellulose-Based Superabsorbent Polymer Gel Crosslinked with Magnesium Aluminum Silicate for Highly Removal of Zn (II) from Aqueous Solution An, Yuhong Zhang, Wanqi Liu, Hui Zhong, Yuan Hu, Zichu Shao, Yali Chen, Zhangjing Ren, Yukun Wang, Boyun Wang, Sunguo Zhang, Xiaotao Wang, Ximing Polymers (Basel) Article Lignocellulose (LCE) was ultrasonically treated and intercalated into magnesium aluminum silicate (MOT) clay to prepare a nano-lignocellulose magnesium aluminum silicate polymer gel (nano-LCE-MOT) for the removal of Zn (II) from aqueous solution. The product was characterised using nitrogen adsorption/desorption isotherm measurements, Fourier-transform infrared spectroscopy, scanning electron microscopy and energy-dispersive X-ray spectroscopy. The conditions for the adsorption of Zn (II) on nano-LCE-MOT were screened, and adsorption kinetics and isotherm model analysis were carried out to explore the adsorption mechanism and achieve the optimal adsorption of Zn (II). Optimal adsorption was achieved at an initial Zn (II) concentration of 800 mg/L at 60 °C in 160 min at a pH of 4.52. The adsorption kinetics were explored using a pseudo-second-order model, with the isotherm adsorption equilibrium found to conform to the Langmuir model. The maximum adsorption capacity of the nano-LCE-MOT polymer gel toward Zn (II) is 513.48 mg/g. The materials with adsorbed Zn (II) were desorbed using different media, with HCl found to be the most ideal medium to desorb Zn (II). The optimal desorption of Zn (II) was achieved in 0.08 mol/L HCl solution at 65 °C in 60 min. Under these conditions, Zn (II) was almost completely desorbed from the adsorbents, with the adsorption effect after cycling being slightly different from that of the initial adsorption. MDPI 2021-11-28 /pmc/articles/PMC8659497/ /pubmed/34883663 http://dx.doi.org/10.3390/polym13234161 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
An, Yuhong
Zhang, Wanqi
Liu, Hui
Zhong, Yuan
Hu, Zichu
Shao, Yali
Chen, Zhangjing
Ren, Yukun
Wang, Boyun
Wang, Sunguo
Zhang, Xiaotao
Wang, Ximing
Lignocellulose-Based Superabsorbent Polymer Gel Crosslinked with Magnesium Aluminum Silicate for Highly Removal of Zn (II) from Aqueous Solution
title Lignocellulose-Based Superabsorbent Polymer Gel Crosslinked with Magnesium Aluminum Silicate for Highly Removal of Zn (II) from Aqueous Solution
title_full Lignocellulose-Based Superabsorbent Polymer Gel Crosslinked with Magnesium Aluminum Silicate for Highly Removal of Zn (II) from Aqueous Solution
title_fullStr Lignocellulose-Based Superabsorbent Polymer Gel Crosslinked with Magnesium Aluminum Silicate for Highly Removal of Zn (II) from Aqueous Solution
title_full_unstemmed Lignocellulose-Based Superabsorbent Polymer Gel Crosslinked with Magnesium Aluminum Silicate for Highly Removal of Zn (II) from Aqueous Solution
title_short Lignocellulose-Based Superabsorbent Polymer Gel Crosslinked with Magnesium Aluminum Silicate for Highly Removal of Zn (II) from Aqueous Solution
title_sort lignocellulose-based superabsorbent polymer gel crosslinked with magnesium aluminum silicate for highly removal of zn (ii) from aqueous solution
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659497/
https://www.ncbi.nlm.nih.gov/pubmed/34883663
http://dx.doi.org/10.3390/polym13234161
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