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Kinetic Assessment of Mechanical Properties of a Cellulose Board Aged in Mineral Oil and Synthetic Ester

In oil-immersed power transformers, the insulation system is constituted of a dielectric oil–solid combination. The insulation oil generally used is mineral oil; however, this fluid has started to be substituted by natural and synthetic esters due to their higher biodegradability and flash point. Th...

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Autores principales: Fernández-Diego, Cristina, Ortiz, Alfredo, Carrascal, Isidro A., Fernández, Inmaculada, Renedo, Carlos J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659535/
https://www.ncbi.nlm.nih.gov/pubmed/34883653
http://dx.doi.org/10.3390/polym13234150
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author Fernández-Diego, Cristina
Ortiz, Alfredo
Carrascal, Isidro A.
Fernández, Inmaculada
Renedo, Carlos J.
author_facet Fernández-Diego, Cristina
Ortiz, Alfredo
Carrascal, Isidro A.
Fernández, Inmaculada
Renedo, Carlos J.
author_sort Fernández-Diego, Cristina
collection PubMed
description In oil-immersed power transformers, the insulation system is constituted of a dielectric oil–solid combination. The insulation oil generally used is mineral oil; however, this fluid has started to be substituted by natural and synthetic esters due to their higher biodegradability and flash point. The introduction of a new fluid in the insulation system of power transformers requires kinetic models that can estimate the degradation rate of insulation solids. The aim of this work was to go further in quantifying through different kinetic models the deterioration suffered by a commercial cellulose board (PSP 3055), which is one of the solid materials used in the insulation system of oil-filled transformers. The aging study was extended to cellulose board specimens immersed in two different oils (mineral and synthetic ester). It was obtained that there is a lower degradation when synthetic ester is used in the insulation system. Additionally, it can be concluded that the use of mechanical properties to quantify the degradation of the cellulose board through kinetic models provides information about the different behavior shown by PSP 3055 when different fiber direction angles are considered.
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spelling pubmed-86595352021-12-10 Kinetic Assessment of Mechanical Properties of a Cellulose Board Aged in Mineral Oil and Synthetic Ester Fernández-Diego, Cristina Ortiz, Alfredo Carrascal, Isidro A. Fernández, Inmaculada Renedo, Carlos J. Polymers (Basel) Article In oil-immersed power transformers, the insulation system is constituted of a dielectric oil–solid combination. The insulation oil generally used is mineral oil; however, this fluid has started to be substituted by natural and synthetic esters due to their higher biodegradability and flash point. The introduction of a new fluid in the insulation system of power transformers requires kinetic models that can estimate the degradation rate of insulation solids. The aim of this work was to go further in quantifying through different kinetic models the deterioration suffered by a commercial cellulose board (PSP 3055), which is one of the solid materials used in the insulation system of oil-filled transformers. The aging study was extended to cellulose board specimens immersed in two different oils (mineral and synthetic ester). It was obtained that there is a lower degradation when synthetic ester is used in the insulation system. Additionally, it can be concluded that the use of mechanical properties to quantify the degradation of the cellulose board through kinetic models provides information about the different behavior shown by PSP 3055 when different fiber direction angles are considered. MDPI 2021-11-27 /pmc/articles/PMC8659535/ /pubmed/34883653 http://dx.doi.org/10.3390/polym13234150 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Fernández-Diego, Cristina
Ortiz, Alfredo
Carrascal, Isidro A.
Fernández, Inmaculada
Renedo, Carlos J.
Kinetic Assessment of Mechanical Properties of a Cellulose Board Aged in Mineral Oil and Synthetic Ester
title Kinetic Assessment of Mechanical Properties of a Cellulose Board Aged in Mineral Oil and Synthetic Ester
title_full Kinetic Assessment of Mechanical Properties of a Cellulose Board Aged in Mineral Oil and Synthetic Ester
title_fullStr Kinetic Assessment of Mechanical Properties of a Cellulose Board Aged in Mineral Oil and Synthetic Ester
title_full_unstemmed Kinetic Assessment of Mechanical Properties of a Cellulose Board Aged in Mineral Oil and Synthetic Ester
title_short Kinetic Assessment of Mechanical Properties of a Cellulose Board Aged in Mineral Oil and Synthetic Ester
title_sort kinetic assessment of mechanical properties of a cellulose board aged in mineral oil and synthetic ester
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659535/
https://www.ncbi.nlm.nih.gov/pubmed/34883653
http://dx.doi.org/10.3390/polym13234150
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