Fabricating Na/In/C Composite Anode with Natrophilic Na–In Alloy Enables Superior Na Ion Deposition in the EC/PC Electrolyte

In conventional ethylene carbonate (EC)/propylene carbonate (PC) electrolyte, sodium metal reacts spontaneously and deleteriously with solvent molecules. This significantly limits the practical feasibility of high-voltage sodium metal batteries based on Na metal chemistry. Herein, we present a sodium metal alloy strategy via introducing NaIn and Na(2)In phases in a Na/In/C composite, aiming at boosting Na ion deposition stability in the common EC/PC electrolyte. Symmetric cells with Na/In/C electrodes achieve an impressive long-term cycling capability at 1 mA cm(−2) (> 870 h) and 5 mA cm(−2) (> 560 h), respectively, with a capacity of 1 mAh cm(−2). In situ optical microscopy clearly unravels a stable Na ion dynamic deposition process on the Na/In/C composite electrode surface, attributing to a dendrite-free and smooth morphology. Furthermore, theoretical simulations reveal intrinsic mechanism for the reversible Na ion deposition behavior with the composite Na/In/C electrode. Upon pairing with a high-voltage NaVPOF cathode, Na/In/C anode illustrates a better suitability in SMBs. This work promises an alternative alloying strategy for enhancing Na metal interfacial stability in the common EC/PC electrolyte for their future applications. [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40820-021-00756-7.