Catalytic Synthesis of 1H-2-Benzoxocins: Cobalt(III)-Carbene Radical Approach to 8-Membered Heterocyclic Enol Ethers

[Image: see text] The metallo-radical activation of ortho-allylcarbonyl-aryl N-arylsulfonylhydrazones with the paramagnetic cobalt(II) porphyrin catalyst [Co(II)(TPP)] (TPP = tetraphenylporphyrin) provides an efficient and powerful method for the synthesis of novel 8-membered heterocyclic enol ether...

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Detalles Bibliográficos
Autores principales: Zhou, Minghui, Wolzak, Lukas A., Li, Zirui, de Zwart, Felix J., Mathew, Simon, de Bruin, Bas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8662738/
https://www.ncbi.nlm.nih.gov/pubmed/34802239
http://dx.doi.org/10.1021/jacs.1c10927

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