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Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes
Controlling the properties of heavy element complexes, such as those containing berkelium, is challenging because relativistic effects, spin-orbit and ligand-field splitting, and complex metal-ligand bonding, all dictate the final electronic states of the molecules. While the first two of these are...
Autores principales: | Gaiser, Alyssa N., Celis-Barros, Cristian, White, Frankie D., Beltran-Leiva, Maria J., Sperling, Joseph M., Salpage, Sahan R., Poe, Todd N., Gomez Martinez, Daniela, Jian, Tian, Wolford, Nikki J., Jones, Nathaniel J., Ritz, Amanda J., Lazenby, Robert A., Gibson, John K., Baumbach, Ryan E., Páez-Hernández, Dayán, Neidig, Michael L., Albrecht-Schönzart, Thomas E. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8664847/ https://www.ncbi.nlm.nih.gov/pubmed/34893651 http://dx.doi.org/10.1038/s41467-021-27576-y |
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