Divergent functionalization of aldehydes photocatalyzed by neutral eosin Y with sulfone reagents

While aldehydes represent a classic class of electrophilic synthons, the corresponding acyl radicals are inherently nucleophilic, which exhibits umpolung reactivity. Generation of acyl radicals typically requires noble metal catalysts or excess oxidants to be added. Herein, we report a convenient an...

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Detalles Bibliográficos
Autores principales: Yan, Jianming, Tang, Haidi, Kuek, Eugene Jun Rong, Shi, Xiangcheng, Liu, Chenguang, Zhang, Muliang, Piper, Jared L., Duan, Shengquan, Wu, Jie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8664905/
https://www.ncbi.nlm.nih.gov/pubmed/34893628
http://dx.doi.org/10.1038/s41467-021-27550-8

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8664905/
https://www.ncbi.nlm.nih.gov/pubmed/34893628
http://dx.doi.org/10.1038/s41467-021-27550-8

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