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Divergent functionalization of aldehydes photocatalyzed by neutral eosin Y with sulfone reagents
While aldehydes represent a classic class of electrophilic synthons, the corresponding acyl radicals are inherently nucleophilic, which exhibits umpolung reactivity. Generation of acyl radicals typically requires noble metal catalysts or excess oxidants to be added. Herein, we report a convenient an...
Autores principales: | Yan, Jianming, Tang, Haidi, Kuek, Eugene Jun Rong, Shi, Xiangcheng, Liu, Chenguang, Zhang, Muliang, Piper, Jared L., Duan, Shengquan, Wu, Jie |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8664905/ https://www.ncbi.nlm.nih.gov/pubmed/34893628 http://dx.doi.org/10.1038/s41467-021-27550-8 |
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