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Chemoselectivity-independent Cu-mediated coupling to construct the hydroquinoline skeleton of symbioimine
Construction of the hydroquinoline skeleton of symbioimine by Cu-mediated N-alkenylation or O-alkenylation of an allyl aminoalcohol, in which either chemoselectivity could lead to the target compound, was investigated. O-alkenylation followed by Claisen rearrangement was favored with high selectivit...
Autores principales: | Fujita, Rie, Hanaya, Kengo, Sugai, Takeshi, Higashibayashi, Shuhei |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8674349/ https://www.ncbi.nlm.nih.gov/pubmed/34911981 http://dx.doi.org/10.1038/s41598-021-03448-9 |
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