Recent Advancements in Nontoxic Halide Perovskites: Beyond Divalent Composition Space

[Image: see text] Since the inception of organic–inorganic hybrid perovskites of ABX(3) stoichiometry in 2009, there has been enormous progress in envisaging efficient solar cell materials throughout the world, from both the theoretical and experimental perspectives. Despite achieving 25.5% efficiency, hybrid halide perovskites are still facing two main challenges: toxicity due to the presence of lead and device stability. Two particular families with A(3)B(2)X(9) and A(2)MM′X(6) stoichiometries have emerged to address these two prime concerns, which have restrained the advancement of solar energy harvesting. Several investigations, both experimental and theoretical, are being conducted to explore the holy-grail materials, which could be optimum for not only efficient but also stable and nontoxic photovoltaics technology. However, the trade-off among stability, efficiency, and toxicity in such solar energy materials is yet to be completely resolved, which requires a systematic overview of A(3)B(2)X(9)- and A(2)MM′X(6)-based solar cell materials. Therefore, in this timely and relevant perspective, we have focused on these two particular promising families of perovskite materials. We have portrayed a roadmap projecting the recent advancements from both theoretical and experimental perspectives for these two exciting and promising solar energy material families while amalgamating our critical viewpoint with a future outlook.