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Synthesis and Oligomerization of CpM(CO)(2)
[Image: see text] We showcase efficient synthetic protocols of cyclopentadienyl metal dicarbonyl, CpM(CO)(2) (M = Rh and Ir). Reflecting the relativistic effect, the (1)H and (13)C signals of the Cp ring in CpIr(CO)(2) were upfield shifted when compared with the Rh analogue. A missing dinuclear comp...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8675160/ https://www.ncbi.nlm.nih.gov/pubmed/34926961 http://dx.doi.org/10.1021/acsomega.1c05739 |