Study on the interactions between melamine-cored Schiff bases with cucurbit[n]urils of different sizes and its application in detecting silver ions

Three different complexes, TMeQ[6]-TBT, Q[7]-TBT, and Q[8]-TBT are constructed by three different cucurbiturils and synthesized by guest melamine-cored Schiff bases (TBT) through outer-surface interaction and host–guest interactions. TBT forms a TMeQ[6]-TBT complex with TMeQ[6] through outer-surface...

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Autores principales: Gou, Jun-Xian, Luo, Yang, Yang, Xi-Nan, Zhang, Wei, Lu, Ji-Hong, Tao, Zhu, Xiao, Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2021
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8685555/
https://www.ncbi.nlm.nih.gov/pubmed/34956415
http://dx.doi.org/10.3762/bjoc.17.204
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author Gou, Jun-Xian
Luo, Yang
Yang, Xi-Nan
Zhang, Wei
Lu, Ji-Hong
Tao, Zhu
Xiao, Xin
author_facet Gou, Jun-Xian
Luo, Yang
Yang, Xi-Nan
Zhang, Wei
Lu, Ji-Hong
Tao, Zhu
Xiao, Xin
author_sort Gou, Jun-Xian
collection PubMed
description Three different complexes, TMeQ[6]-TBT, Q[7]-TBT, and Q[8]-TBT are constructed by three different cucurbiturils and synthesized by guest melamine-cored Schiff bases (TBT) through outer-surface interaction and host–guest interactions. TBT forms a TMeQ[6]-TBT complex with TMeQ[6] through outer-surface interaction, while Q[7]-TBT and Q[8]-TBT form complexes with Q[7,8] through host–guest interactions. Among them, Q[7]-TBT is selected as a UV detector for the detection of silver ions (Ag(+)). This work makes full use of the characteristics of each cucurbituril and melamine-cored Schiff base to construct a series of complexes and these are applied to metal detection.
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spelling pubmed-86855552021-12-23 Study on the interactions between melamine-cored Schiff bases with cucurbit[n]urils of different sizes and its application in detecting silver ions Gou, Jun-Xian Luo, Yang Yang, Xi-Nan Zhang, Wei Lu, Ji-Hong Tao, Zhu Xiao, Xin Beilstein J Org Chem Full Research Paper Three different complexes, TMeQ[6]-TBT, Q[7]-TBT, and Q[8]-TBT are constructed by three different cucurbiturils and synthesized by guest melamine-cored Schiff bases (TBT) through outer-surface interaction and host–guest interactions. TBT forms a TMeQ[6]-TBT complex with TMeQ[6] through outer-surface interaction, while Q[7]-TBT and Q[8]-TBT form complexes with Q[7,8] through host–guest interactions. Among them, Q[7]-TBT is selected as a UV detector for the detection of silver ions (Ag(+)). This work makes full use of the characteristics of each cucurbituril and melamine-cored Schiff base to construct a series of complexes and these are applied to metal detection. Beilstein-Institut 2021-12-17 /pmc/articles/PMC8685555/ /pubmed/34956415 http://dx.doi.org/10.3762/bjoc.17.204 Text en Copyright © 2021, Gou et al. https://creativecommons.org/licenses/by/4.0/This is an open access article licensed under the terms of the Beilstein-Institut Open Access License Agreement (https://www.beilstein-journals.org/bjoc/terms/terms), which is identical to the Creative Commons Attribution 4.0 International License (https://creativecommons.org/licenses/by/4.0 (https://creativecommons.org/licenses/by/4.0/) ). The reuse of material under this license requires that the author(s), source and license are credited. Third-party material in this article could be subject to other licenses (typically indicated in the credit line), and in this case, users are required to obtain permission from the license holder to reuse the material.
spellingShingle Full Research Paper
Gou, Jun-Xian
Luo, Yang
Yang, Xi-Nan
Zhang, Wei
Lu, Ji-Hong
Tao, Zhu
Xiao, Xin
Study on the interactions between melamine-cored Schiff bases with cucurbit[n]urils of different sizes and its application in detecting silver ions
title Study on the interactions between melamine-cored Schiff bases with cucurbit[n]urils of different sizes and its application in detecting silver ions
title_full Study on the interactions between melamine-cored Schiff bases with cucurbit[n]urils of different sizes and its application in detecting silver ions
title_fullStr Study on the interactions between melamine-cored Schiff bases with cucurbit[n]urils of different sizes and its application in detecting silver ions
title_full_unstemmed Study on the interactions between melamine-cored Schiff bases with cucurbit[n]urils of different sizes and its application in detecting silver ions
title_short Study on the interactions between melamine-cored Schiff bases with cucurbit[n]urils of different sizes and its application in detecting silver ions
title_sort study on the interactions between melamine-cored schiff bases with cucurbit[n]urils of different sizes and its application in detecting silver ions
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8685555/
https://www.ncbi.nlm.nih.gov/pubmed/34956415
http://dx.doi.org/10.3762/bjoc.17.204
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