Generation of Tosyl Azide in Continuous Flow Using an Azide Resin, and Telescoping with Diazo Transfer and Rhodium Acetate-Catalyzed O–H Insertion

[Image: see text] Generation of tosyl azide 12 in acetonitrile in flow under water-free conditions using an azide resin and its use in diazo transfer to a series of aryl acetates are described. Successful telescoping with a rhodium acetate-catalyzed O–H insertion has been achieved, thereby transform...

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Detalles Bibliográficos
Autores principales: O’Mahony, Rosella M., Lynch, Denis, O’Callaghan, Katie S., Collins, Stuart G., Maguire, Anita R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8689650/
https://www.ncbi.nlm.nih.gov/pubmed/34955628
http://dx.doi.org/10.1021/acs.oprd.1c00377

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8689650/
https://www.ncbi.nlm.nih.gov/pubmed/34955628
http://dx.doi.org/10.1021/acs.oprd.1c00377

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