Tracking the Transition from Pericyclic to Pseudopericyclic Reaction Mechanisms Using Multicenter Electron Delocalization Analysis: The [1,3] Sigmatropic Rearrangement

[Image: see text] Herein, the power of multicenter electron delocalization analysis to elucidate the intricacies of concerted reaction mechanisms is brought to light by tracking the transition of [1,3] sigmatropic rearrangements from the high-barrier pericyclic mechanism in 1-butene to the barrierle...

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Detalles Bibliográficos
Autores principales: Pérez-Barcia, Álvaro, Peña-Gallego, Ángeles, Mandado, Marcos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8693182/
https://www.ncbi.nlm.nih.gov/pubmed/34510896
http://dx.doi.org/10.1021/acs.jpca.1c06620

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8693182/
https://www.ncbi.nlm.nih.gov/pubmed/34510896
http://dx.doi.org/10.1021/acs.jpca.1c06620

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