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The synthesis and characterization of the octahedral Co(III) complex of a pyrrolopyrrolizine derivative formed with dicyanovinylene-bis-(meso-aryl)dipyrrin
A low spin state and diamagnetic Co(III) complex 1 possessing pyrrolopyrrolizine ligands formed with dicyanovinylene-bis-(meso-aryl)dipyrrin was synthesized via the thermally activated metalation with CoCl(2) and isolated via column chromatography. The nuclear magnetic resonance of complex 1 reveale...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8693670/ https://www.ncbi.nlm.nih.gov/pubmed/35424195 http://dx.doi.org/10.1039/d0ra09452h |