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A short, versatile route towards benzothiadiazinyl radicals

A family of substituted 1,2,4-benzothiadiazine 1-chlorides have been prepared by treatment of N-arylamidines in neat thionyl chloride at reflux. The S(iv) 1-chlorides are readily reduced under mild conditions to persistent 1,2,4-benzothiadiazinyl radicals which have been characterised by EPR spectro...

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Detalles Bibliográficos
Autores principales: Borys, Andryj M., Clark, Ewan R., Saines, Paul J., Alberola, Antonio, Rawson, Jeremy M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8694340/
https://www.ncbi.nlm.nih.gov/pubmed/35059163
http://dx.doi.org/10.1039/d1sc04248c