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Niobium- and zirconium-catalyzed reactions of substituted 2 alkynylamines with Et(2)Zn

The NbCl(5)–EtMgBr-catalyzed reaction of N,N-disubstituted 2-alkynylamines with Et(2)Zn followed by hydrolysis or deuterolysis affords (2Z)-alkenylamines (reduction products of alkyne) in high yields. The reaction of N,N-disubstituted 2-alkynylamines with Et(2)Zn catalyzed by the Cp(2)ZrCl(2)–EtMgBr...

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Detalles Bibliográficos
Autores principales: Kadikova, Rita N., Ramazanov, Ilfir R., Gabdullin, Azat M., Mozgovoj, Oleg S., Dzhemilev, Usein M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8694551/
https://www.ncbi.nlm.nih.gov/pubmed/35424400
http://dx.doi.org/10.1039/d0ra10132j