Silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability

Molybdenum dinitrogen complexes supported by monodentate arylsilylamido ligand, [Ar(Me(3)Si)N](3)MoN(2)Mg(THF)(2)[N(SiMe(3))Ar] (5) and [Ar(Me(3)Si)N](3)MoN(2)SiMe(3) (6) (Ar = 3,5-Me(2)C(6)H(3)) were synthesized and structurally characterized, and proved to be effective catalysts for the disproport...

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Detalles Bibliográficos
Autores principales: Zhai, Dan-dan, Xie, Si-jun, Xia, Yi, Fang, Hua-yi, Shi, Zhang-jie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Oxford University Press 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8694672/
https://www.ncbi.nlm.nih.gov/pubmed/34987834
http://dx.doi.org/10.1093/nsr/nwaa290
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author Zhai, Dan-dan
Xie, Si-jun
Xia, Yi
Fang, Hua-yi
Shi, Zhang-jie
author_facet Zhai, Dan-dan
Xie, Si-jun
Xia, Yi
Fang, Hua-yi
Shi, Zhang-jie
author_sort Zhai, Dan-dan
collection PubMed
description Molybdenum dinitrogen complexes supported by monodentate arylsilylamido ligand, [Ar(Me(3)Si)N](3)MoN(2)Mg(THF)(2)[N(SiMe(3))Ar] (5) and [Ar(Me(3)Si)N](3)MoN(2)SiMe(3) (6) (Ar = 3,5-Me(2)C(6)H(3)) were synthesized and structurally characterized, and proved to be effective catalysts for the disproportionation of cyclohexadienes and isomerization of terminal alkenes. The (1)H NMR spectrum suggested that the bridging nitrogen ligand remains intact during the catalytic reaction, indicating possible catalytic ability of the Mo-N=N motif.
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spelling pubmed-86946722022-01-04 Silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability Zhai, Dan-dan Xie, Si-jun Xia, Yi Fang, Hua-yi Shi, Zhang-jie Natl Sci Rev Chemistry Molybdenum dinitrogen complexes supported by monodentate arylsilylamido ligand, [Ar(Me(3)Si)N](3)MoN(2)Mg(THF)(2)[N(SiMe(3))Ar] (5) and [Ar(Me(3)Si)N](3)MoN(2)SiMe(3) (6) (Ar = 3,5-Me(2)C(6)H(3)) were synthesized and structurally characterized, and proved to be effective catalysts for the disproportionation of cyclohexadienes and isomerization of terminal alkenes. The (1)H NMR spectrum suggested that the bridging nitrogen ligand remains intact during the catalytic reaction, indicating possible catalytic ability of the Mo-N=N motif. Oxford University Press 2020-12-03 /pmc/articles/PMC8694672/ /pubmed/34987834 http://dx.doi.org/10.1093/nsr/nwaa290 Text en © The Author(s) 2020. Published by Oxford University Press on behalf of China Science Publishing & Media Ltd. https://creativecommons.org/licenses/by/4.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Zhai, Dan-dan
Xie, Si-jun
Xia, Yi
Fang, Hua-yi
Shi, Zhang-jie
Silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability
title Silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability
title_full Silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability
title_fullStr Silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability
title_full_unstemmed Silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability
title_short Silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability
title_sort silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8694672/
https://www.ncbi.nlm.nih.gov/pubmed/34987834
http://dx.doi.org/10.1093/nsr/nwaa290
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