Synthesis and self-assembly of a penta[60]fullerene bearing benzo[ghi]perylenetriimide units

A benzo[ghi]perylenetriimide (BPTI) derivative bearing a terminal azido group on the expanded π-conjugated backbone has been synthesized and characterized. This promising photo- and electroactive BPTI motif has been used to obtain an original penta(organo)fullerene as a promising multi-electron acce...

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Detalles Bibliográficos
Autores principales: Drou, Clément, Merland, Théo, Busseau, Antoine, Dabos-Seignon, Sylvie, Goujon, Antoine, Hudhomme, Piétrick, Benyahia, Lazhar, Chassenieux, Christophe, Legoupy, Stéphanie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8694833/
https://www.ncbi.nlm.nih.gov/pubmed/35423142
http://dx.doi.org/10.1039/d1ra00287b
Descripción
Sumario:A benzo[ghi]perylenetriimide (BPTI) derivative bearing a terminal azido group on the expanded π-conjugated backbone has been synthesized and characterized. This promising photo- and electroactive BPTI motif has been used to obtain an original penta(organo)fullerene as a promising multi-electron acceptor system. Our studies show its self-assembly resulting from aggregation via π–π stacking interaction in solution and in the solid state.

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