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Aerobically stable and substitutionally labile α-diimine rhenium dicarbonyl complexes
New synthetic routes to aerobically stable and substitutionally labile α-diimine rhenium(i) dicarbonyl complexes are described. The molecules are prepared in high yield from the cis–cis–trans-[Re(CO)(2)((t)Bu(2)bpy)Br(2)](−) anion (2, where (t)Bu(2)bpy is 4,4′-di-tert-butyl-2,2′-bipyridine), which c...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8694950/ https://www.ncbi.nlm.nih.gov/pubmed/35423250 http://dx.doi.org/10.1039/d1ra00514f |