2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane as a useful precursor to 2,3-dimethylene-1,4-dioxane for [4+2] cycloaddition reaction

2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane readily prepared from biacetyl serves as a stable precursor to 2,3-dimethylene-1,4-dioxane which undergoes a [4+2] cycloaddition reaction with dienophiles to give functionalized cyclohexene derivatives. The cycloaddition adducts obtained by the present procedur...

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Detalles Bibliográficos
Autores principales: Shimizu, Makoto, Yamamoto, Toshihiro, Shindo, Hiroaki, Mizota, Isao, Zhu, Yusong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695070/
https://www.ncbi.nlm.nih.gov/pubmed/35423349
http://dx.doi.org/10.1039/d1ra00329a
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author Shimizu, Makoto
Yamamoto, Toshihiro
Shindo, Hiroaki
Mizota, Isao
Zhu, Yusong
author_facet Shimizu, Makoto
Yamamoto, Toshihiro
Shindo, Hiroaki
Mizota, Isao
Zhu, Yusong
author_sort Shimizu, Makoto
collection PubMed
description 2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane readily prepared from biacetyl serves as a stable precursor to 2,3-dimethylene-1,4-dioxane which undergoes a [4+2] cycloaddition reaction with dienophiles to give functionalized cyclohexene derivatives. The cycloaddition adducts obtained by the present procedure are transformed into potentially useful intermediates for biologically important materials.
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spelling pubmed-86950702022-04-13 2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane as a useful precursor to 2,3-dimethylene-1,4-dioxane for [4+2] cycloaddition reaction Shimizu, Makoto Yamamoto, Toshihiro Shindo, Hiroaki Mizota, Isao Zhu, Yusong RSC Adv Chemistry 2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane readily prepared from biacetyl serves as a stable precursor to 2,3-dimethylene-1,4-dioxane which undergoes a [4+2] cycloaddition reaction with dienophiles to give functionalized cyclohexene derivatives. The cycloaddition adducts obtained by the present procedure are transformed into potentially useful intermediates for biologically important materials. The Royal Society of Chemistry 2021-02-18 /pmc/articles/PMC8695070/ /pubmed/35423349 http://dx.doi.org/10.1039/d1ra00329a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Shimizu, Makoto
Yamamoto, Toshihiro
Shindo, Hiroaki
Mizota, Isao
Zhu, Yusong
2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane as a useful precursor to 2,3-dimethylene-1,4-dioxane for [4+2] cycloaddition reaction
title 2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane as a useful precursor to 2,3-dimethylene-1,4-dioxane for [4+2] cycloaddition reaction
title_full 2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane as a useful precursor to 2,3-dimethylene-1,4-dioxane for [4+2] cycloaddition reaction
title_fullStr 2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane as a useful precursor to 2,3-dimethylene-1,4-dioxane for [4+2] cycloaddition reaction
title_full_unstemmed 2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane as a useful precursor to 2,3-dimethylene-1,4-dioxane for [4+2] cycloaddition reaction
title_short 2,3-Dimethoxy-2,3-dimethyl-1,4-dioxane as a useful precursor to 2,3-dimethylene-1,4-dioxane for [4+2] cycloaddition reaction
title_sort 2,3-dimethoxy-2,3-dimethyl-1,4-dioxane as a useful precursor to 2,3-dimethylene-1,4-dioxane for [4+2] cycloaddition reaction
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695070/
https://www.ncbi.nlm.nih.gov/pubmed/35423349
http://dx.doi.org/10.1039/d1ra00329a
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