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Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects

The synthesis of polymers using elemental sulphur as a chemical agent has been studied in relation to the worldwide overproduction of cyclo-octasulphur. Herein, the mechanisms of the processes leading to the inclusion of elemental sulphur into macromolecules have been reviewed and the main methods f...

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Autores principales: Tarasova, Natalia P., Zanin, Alexey A., Krivoborodov, Efrem G., Mezhuev, Yaroslav O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695231/
https://www.ncbi.nlm.nih.gov/pubmed/35423353
http://dx.doi.org/10.1039/d0ra10507d
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author Tarasova, Natalia P.
Zanin, Alexey A.
Krivoborodov, Efrem G.
Mezhuev, Yaroslav O.
author_facet Tarasova, Natalia P.
Zanin, Alexey A.
Krivoborodov, Efrem G.
Mezhuev, Yaroslav O.
author_sort Tarasova, Natalia P.
collection PubMed
description The synthesis of polymers using elemental sulphur as a chemical agent has been studied in relation to the worldwide overproduction of cyclo-octasulphur. Herein, the mechanisms of the processes leading to the inclusion of elemental sulphur into macromolecules have been reviewed and the main methods for reduction of the reaction temperature required for the S(8) ring opening have been shown. Approaches to the activation of cyclo-octasulphur in the synthesis and macromolecule cross-linking reactions were discussed in the context of finding the chemical agents and conditions that satisfy the principles of green chemistry.
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spelling pubmed-86952312022-04-13 Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects Tarasova, Natalia P. Zanin, Alexey A. Krivoborodov, Efrem G. Mezhuev, Yaroslav O. RSC Adv Chemistry The synthesis of polymers using elemental sulphur as a chemical agent has been studied in relation to the worldwide overproduction of cyclo-octasulphur. Herein, the mechanisms of the processes leading to the inclusion of elemental sulphur into macromolecules have been reviewed and the main methods for reduction of the reaction temperature required for the S(8) ring opening have been shown. Approaches to the activation of cyclo-octasulphur in the synthesis and macromolecule cross-linking reactions were discussed in the context of finding the chemical agents and conditions that satisfy the principles of green chemistry. The Royal Society of Chemistry 2021-03-01 /pmc/articles/PMC8695231/ /pubmed/35423353 http://dx.doi.org/10.1039/d0ra10507d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Tarasova, Natalia P.
Zanin, Alexey A.
Krivoborodov, Efrem G.
Mezhuev, Yaroslav O.
Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects
title Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects
title_full Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects
title_fullStr Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects
title_full_unstemmed Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects
title_short Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects
title_sort elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695231/
https://www.ncbi.nlm.nih.gov/pubmed/35423353
http://dx.doi.org/10.1039/d0ra10507d
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