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Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects
The synthesis of polymers using elemental sulphur as a chemical agent has been studied in relation to the worldwide overproduction of cyclo-octasulphur. Herein, the mechanisms of the processes leading to the inclusion of elemental sulphur into macromolecules have been reviewed and the main methods f...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695231/ https://www.ncbi.nlm.nih.gov/pubmed/35423353 http://dx.doi.org/10.1039/d0ra10507d |
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author | Tarasova, Natalia P. Zanin, Alexey A. Krivoborodov, Efrem G. Mezhuev, Yaroslav O. |
author_facet | Tarasova, Natalia P. Zanin, Alexey A. Krivoborodov, Efrem G. Mezhuev, Yaroslav O. |
author_sort | Tarasova, Natalia P. |
collection | PubMed |
description | The synthesis of polymers using elemental sulphur as a chemical agent has been studied in relation to the worldwide overproduction of cyclo-octasulphur. Herein, the mechanisms of the processes leading to the inclusion of elemental sulphur into macromolecules have been reviewed and the main methods for reduction of the reaction temperature required for the S(8) ring opening have been shown. Approaches to the activation of cyclo-octasulphur in the synthesis and macromolecule cross-linking reactions were discussed in the context of finding the chemical agents and conditions that satisfy the principles of green chemistry. |
format | Online Article Text |
id | pubmed-8695231 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-86952312022-04-13 Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects Tarasova, Natalia P. Zanin, Alexey A. Krivoborodov, Efrem G. Mezhuev, Yaroslav O. RSC Adv Chemistry The synthesis of polymers using elemental sulphur as a chemical agent has been studied in relation to the worldwide overproduction of cyclo-octasulphur. Herein, the mechanisms of the processes leading to the inclusion of elemental sulphur into macromolecules have been reviewed and the main methods for reduction of the reaction temperature required for the S(8) ring opening have been shown. Approaches to the activation of cyclo-octasulphur in the synthesis and macromolecule cross-linking reactions were discussed in the context of finding the chemical agents and conditions that satisfy the principles of green chemistry. The Royal Society of Chemistry 2021-03-01 /pmc/articles/PMC8695231/ /pubmed/35423353 http://dx.doi.org/10.1039/d0ra10507d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Tarasova, Natalia P. Zanin, Alexey A. Krivoborodov, Efrem G. Mezhuev, Yaroslav O. Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects |
title | Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects |
title_full | Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects |
title_fullStr | Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects |
title_full_unstemmed | Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects |
title_short | Elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects |
title_sort | elemental sulphur in the synthesis of sulphur-containing polymers: reaction mechanisms and green prospects |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695231/ https://www.ncbi.nlm.nih.gov/pubmed/35423353 http://dx.doi.org/10.1039/d0ra10507d |
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