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Monoallylation and benzylation of dicarbonyl compounds with alcohols catalysed by a cationic cobalt(iii) compound
Monoallylation and monoalkylation of diketones and β-keto esters with allylic and benzylic alcohols catalysed by [Cp*Co(CH(3)CN)(3)][SbF(6)](2) (I) are reported. The method does not require any additive and affords regioselective products. The mechanistic investigations were done by in situ(1)H NMR...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695336/ https://www.ncbi.nlm.nih.gov/pubmed/35423451 http://dx.doi.org/10.1039/d0ra09778k |