A general method for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments

A general approach for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments has been developed through metathesis reactions between amine chloroborane complexes and potassium salt of trinitromethyl (K[C(NO(2))(3)]). Five covalent and ionic trinitromethyl ami...

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Detalles Bibliográficos
Autores principales: Wang, Jin, Ju, Ming-Yue, Chen, Xi-Meng, Chen, Xuenian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695509/
https://www.ncbi.nlm.nih.gov/pubmed/35423463
http://dx.doi.org/10.1039/d1ra00440a
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author Wang, Jin
Ju, Ming-Yue
Chen, Xi-Meng
Chen, Xuenian
author_facet Wang, Jin
Ju, Ming-Yue
Chen, Xi-Meng
Chen, Xuenian
author_sort Wang, Jin
collection PubMed
description A general approach for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments has been developed through metathesis reactions between amine chloroborane complexes and potassium salt of trinitromethyl (K[C(NO(2))(3)]). Five covalent and ionic trinitromethyl amine borane complexes have been synthesized in good yields with high purity and it is found that the ionic complex, [H(2)B(NH(3))(2)][C(NO(2))(3)], might be a promising energetic material on the basis of the investigation of its thermal decomposition behaviour.
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spelling pubmed-86955092022-04-13 A general method for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments Wang, Jin Ju, Ming-Yue Chen, Xi-Meng Chen, Xuenian RSC Adv Chemistry A general approach for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments has been developed through metathesis reactions between amine chloroborane complexes and potassium salt of trinitromethyl (K[C(NO(2))(3)]). Five covalent and ionic trinitromethyl amine borane complexes have been synthesized in good yields with high purity and it is found that the ionic complex, [H(2)B(NH(3))(2)][C(NO(2))(3)], might be a promising energetic material on the basis of the investigation of its thermal decomposition behaviour. The Royal Society of Chemistry 2021-03-05 /pmc/articles/PMC8695509/ /pubmed/35423463 http://dx.doi.org/10.1039/d1ra00440a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Wang, Jin
Ju, Ming-Yue
Chen, Xi-Meng
Chen, Xuenian
A general method for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments
title A general method for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments
title_full A general method for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments
title_fullStr A general method for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments
title_full_unstemmed A general method for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments
title_short A general method for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments
title_sort general method for the synthesis of covalent and ionic amine borane complexes containing trinitromethyl fragments
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695509/
https://www.ncbi.nlm.nih.gov/pubmed/35423463
http://dx.doi.org/10.1039/d1ra00440a
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