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In situ electrochemical activation as a generic strategy for promoting the electrocatalytic hydrogen evolution reaction and alcohol electro-oxidation in alkaline medium

In situ electrochemical activation as a new pre-treatment method is extremely effective for enhanced electrocatalytic performances for different applications. With the help of this method, in situ surface modification of electrocatalyst is achieved without using pre-made seeds or complex synthesis p...

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Detalles Bibliográficos
Autores principales: Kardan, Alireza, Ashraf, Narges, Dabirifar, Zeynab, Khadempir, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695632/
https://www.ncbi.nlm.nih.gov/pubmed/35423543
http://dx.doi.org/10.1039/d0ra07817d
Descripción
Sumario:In situ electrochemical activation as a new pre-treatment method is extremely effective for enhanced electrocatalytic performances for different applications. With the help of this method, in situ surface modification of electrocatalyst is achieved without using pre-made seeds or complex synthesis procedure. Herein, with the purpose of finding an in situ and simple electrochemical activation protocol, the green synthesis of Au/Pd nanoparticles (AuPd) by means of polyoxometalate (POM) is reported. Structural analysis of the AuPd nanohybrid unveil the Au-core/Pd-shell structure which surrounded by POM. We propose a novel cathodic electrochemical activation in phosphate buffer solution which can greatly boost the electrocatalytic activity of the as-prepared AuPd and Pd electrocatalyst not only for hydrogen evolution reaction (HER) as a model of electro-reduction, but also for methanol and ethanol electro-oxidation reaction (MOR & EOR). For the HER in 1 M NaOH solution, after the electrochemical activation, the needed potential to drive a geometrical current density of 10 mA cm(−2) significantly decreases from – 400 mV vs. the reversible hydrogen electrode (RHE) to −290 mV vs. RHE. For the EOR and MOR, electrochemically activated AuPd realized 3.4- and 2.9- fold increase in mass current density (mA mg(Pd)(−1)) with respect to the pristine AuPd electrocatalyst, respectively.