Catalytic enantioselective intramolecular Tishchenko reaction of meso-dialdehyde: synthesis of (S)-cedarmycins

The first successful example of a catalytic enantioselective intramolecular Tishchenko reaction of a meso-dialdehyde in the presence of a chiral iridium complex is described. Chiral lactones were obtained in good yields with up to 91% ee. The obtained enantioenriched lactones were utilized for the f...

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Detalles Bibliográficos
Autores principales: Ismiyarto, Kishi, Nobuki, Adachi, Yuki, Jiang, Rui, Doi, Takahiro, Zhou, Da-Yang, Asano, Kaori, Obora, Yasushi, Suzuki, Takayoshi, Sasai, Hiroaki, Suzuki, Takeyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695919/
https://www.ncbi.nlm.nih.gov/pubmed/35423664
http://dx.doi.org/10.1039/d1ra00915j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695919/
https://www.ncbi.nlm.nih.gov/pubmed/35423664
http://dx.doi.org/10.1039/d1ra00915j

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