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Peripherical thioester functionalization induces J-aggregation in bithiophene-DPP films and nanoparticles

In this work we demonstrated that the peripherical thioacetylation of a bithiophene–DPP molecule can greatly influence the solid-state properties triggering the formation of NIR emitting J-aggregates in both bithiophene–DPP films and nanoparticles. The morphology and the kinetic and thermal stabilit...

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Detalles Bibliográficos
Autores principales: Punzi, Angela, Blasi, Davide, Operamolla, Alessandra, Comparelli, Roberto, Palazzo, Gerardo, Farinola, Gianluca M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695947/
https://www.ncbi.nlm.nih.gov/pubmed/35423602
http://dx.doi.org/10.1039/d1ra01253c
Descripción
Sumario:In this work we demonstrated that the peripherical thioacetylation of a bithiophene–DPP molecule can greatly influence the solid-state properties triggering the formation of NIR emitting J-aggregates in both bithiophene–DPP films and nanoparticles. The morphology and the kinetic and thermal stability of the organic nanoparticles were also investigated.